Fully integrated CO₂ mitigation strategy for an existing refinery:A case study in Colombia

The oil and gas industry is responsible for 6% of total global CO2 emissions, from exploration to downstream petrochemical production and account for another 50% when including the use of its products. Thus, this industry has a significant role in realising the target of net “zero” CO2 emissions by 2070, essential to limit global warming to 1.8 °C [2], as introduced under the Paris agreement. Currently, the interactions of an extensive set of individual and combined CO2 mitigation measures along the value chain and over time are poorly assessed. This paper aims to assess a bottom-up CO2 mitigation potential for a complex refinery, including portfolios of combined mitigation options, considering synergies, overlap, and interactions over time for more realistic insight into the costs and constraints of the mitigation portfolio. A total of 40 measures were identified, covering a wide range of technologies such as energy efficiency measures (EEM), carbon capture and storage (CCS), bio-oil co-processing, blue and green hydrogen (BH2, GH2), green electricity import, and electrification of refining processes linked to the transition of the Colombian energy systems. Five deployment pathways were assessed to achieve different specific targets: 1-base case scenario, 2-less effort, 3-maximum CO2 avoidance, 4-INDC, and 5-measures below 200 €/t CO2. Two scenarios (3 and 5) gave the highest GHG emission reduction potentials of 106% and 98% of refining process emissions, respectively. Although significant, it represent only around 13% of the life-cycle emissions when including upstream and final-use emissions of the produced fuels. Bio-oil co-processing options account for around 60% of the mitigation options portfolio, followed by CCS (23%), green electricity (7%) and green H2 (6%). The devised methodological approach in this study can also be applied to assess other energy-intensive industrial complexes and shed light on the bias for estimating CO2 mitigation potentials, especially when combining different mitigation options. This is turn is vital to define optimal transition pathways of industrial complexes.