A comprehensive model to describe the water stability of prototypical metal–organic frameworks (MOFs) is derived by combining different types of theoretical and experimental approaches. The results provide an insight into the early stages of water-triggered destabilization of MOFs and allow detailed pathways to be proposed for the degradation of different MOFs under aqueous conditions. The essential elements of the approach are computing the pKa values of coordinated water molecules and geometry relaxations. Variable-temperature and pH infrared spectroscopy techniques are used to corroborate the main findings. The model developed herein helps to explain stability limits observed for several prototypical MOFs, including MOF-5, HKUST-1, UiO-6...
Les Metal-Organic Frameworks (MOF) sont des matériaux hybrides poreux cristallisés constitués de clu...
Highly porous metal–organic frameworks (MOFs), which have undergone exciting developments over the p...
The stability of functional materials in water-containing environments is critical for their industr...
A comprehensive model to describe the water stability of prototypical metal–organic frameworks (MOFs...
Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hyd...
NH2-MIL-125(Ti) is a metal organic framework (MOF) based on Ti-oxo-clusters widely investigated in w...
International audienceWe report an ab initio Molecular Dynamics study of the hydration process in a ...
Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hyd...
Metal-organic frameworks (MOFs) are a relatively new class of porous materials, assembled from inorg...
Metal-organic frameworks (MOFs) are a class of porous inorganic materials with promising properties ...
Metal-organic frameworks (MOFs) are a class of porous inorganic materials with promising properties ...
International audienceFlexible metal–organic frameworks, also known as soft porous crystals, have be...
Metal-organic frameworks (MOFs) are porous networks of metal-centers connect by organic ligands, whi...
As global energy demand increases, breakthroughs in clean energy technologies will be needed to meet...
Metal-organic frameworks (MOFs) are a class of crystalline nanoporous adsorbents with numerous appli...
Les Metal-Organic Frameworks (MOF) sont des matériaux hybrides poreux cristallisés constitués de clu...
Highly porous metal–organic frameworks (MOFs), which have undergone exciting developments over the p...
The stability of functional materials in water-containing environments is critical for their industr...
A comprehensive model to describe the water stability of prototypical metal–organic frameworks (MOFs...
Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hyd...
NH2-MIL-125(Ti) is a metal organic framework (MOF) based on Ti-oxo-clusters widely investigated in w...
International audienceWe report an ab initio Molecular Dynamics study of the hydration process in a ...
Since their discovery a few decades ago, metal–organic frameworks (MOFs) have suffered from poor hyd...
Metal-organic frameworks (MOFs) are a relatively new class of porous materials, assembled from inorg...
Metal-organic frameworks (MOFs) are a class of porous inorganic materials with promising properties ...
Metal-organic frameworks (MOFs) are a class of porous inorganic materials with promising properties ...
International audienceFlexible metal–organic frameworks, also known as soft porous crystals, have be...
Metal-organic frameworks (MOFs) are porous networks of metal-centers connect by organic ligands, whi...
As global energy demand increases, breakthroughs in clean energy technologies will be needed to meet...
Metal-organic frameworks (MOFs) are a class of crystalline nanoporous adsorbents with numerous appli...
Les Metal-Organic Frameworks (MOF) sont des matériaux hybrides poreux cristallisés constitués de clu...
Highly porous metal–organic frameworks (MOFs), which have undergone exciting developments over the p...
The stability of functional materials in water-containing environments is critical for their industr...