Catalytic Asymmetric Synthesis of Mycolipenic and Mycolipanolic Acid

ter Horst, Bjorn
van Wermeskerken, Jeroen
Feringa, Ben L.
Minnaard, Adriaan J.

Publication date

January 2010

DOI

10.1002/ejoc.200901120

Abstract

The first asymmetric synthesis of mycolipenic acid and mycolipanolic acid by using an improved iterative procedure involving catalytic asymmetric conjugate addition of MeMgBr as the key step is described. Mycolipenic and mycolipanolic acid are obtained in 11 steps with perfect stereocontrol, and both acids are identical to their counterparts from natural sources.</p

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Catalytic Asymmetric Synthesis of Mycolipenic and Mycolipanolic Acid

Abstract

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Catalytic Asymmetric Synthesis of Mycolipenic and Mycolipanolic Acid

Abstract

Extracted data

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