In an effort to model solute–solvent interactions, the C=O stretching frequencies of five 1-substituted 2-pyrrolidinones and four other carbonyl-containing compounds were measured for 30 common solvents. These were then correlated with four empirical parameter sets and one theoretical (computational) parameter set. While an empirical parameter set gave the best correlation equations, the theoretical parameter equations are physically and statistically significant. Solvent volume, polarizability and hydrogen bond donor acidity (capacity) terms are significant in the correlation equations
Author Institution: U.S. Naval Research LaboratoryThe effect of solvent-solute interactions on the c...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...
In an effort to model solute–solvent interactions, the C=O stretching frequencies of five 1-substitu...
The carbonyl stretching frequencies of 1-substituted 2-pyrrolidinones and related compounds were mea...
The wavenumbers of the carbonyl stretching vibrations of 2-pyrrolidinone (P), 1-methyl-2-pyrrolidino...
The wavenumbers of the carbonyl stretching vibrations of 2-pyrrolidinone (P), 1-methyl-2-pyrrolidino...
The dependence of nuBAR(C=O) on solvent for N-cyclohexyl-2-pyrrolidinone (NCP) as solute in 18 pure ...
Summary. The wavenumbers of the carbonyl stretching vibrations of 2-pyrrolidinone (P)
Solvent effects on O{single bond}H stretching vibrations in several complexes with hydrogen bonding ...
Solvent effects on O{single bond}H stretching vibrations in several complexes with hydrogen bonding ...
Solvent effects on O{single bond}H stretching vibrations in several complexes with hydrogen bonding ...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...
Solvent effect on the stretching vibration frequencies of the O-H and N-H groups in complexes of phe...
Solvent effect on the stretching vibration frequencies of the O-H and N-H groups in complexes of phe...
Author Institution: U.S. Naval Research LaboratoryThe effect of solvent-solute interactions on the c...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...
In an effort to model solute–solvent interactions, the C=O stretching frequencies of five 1-substitu...
The carbonyl stretching frequencies of 1-substituted 2-pyrrolidinones and related compounds were mea...
The wavenumbers of the carbonyl stretching vibrations of 2-pyrrolidinone (P), 1-methyl-2-pyrrolidino...
The wavenumbers of the carbonyl stretching vibrations of 2-pyrrolidinone (P), 1-methyl-2-pyrrolidino...
The dependence of nuBAR(C=O) on solvent for N-cyclohexyl-2-pyrrolidinone (NCP) as solute in 18 pure ...
Summary. The wavenumbers of the carbonyl stretching vibrations of 2-pyrrolidinone (P)
Solvent effects on O{single bond}H stretching vibrations in several complexes with hydrogen bonding ...
Solvent effects on O{single bond}H stretching vibrations in several complexes with hydrogen bonding ...
Solvent effects on O{single bond}H stretching vibrations in several complexes with hydrogen bonding ...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...
Solvent effect on the stretching vibration frequencies of the O-H and N-H groups in complexes of phe...
Solvent effect on the stretching vibration frequencies of the O-H and N-H groups in complexes of phe...
Author Institution: U.S. Naval Research LaboratoryThe effect of solvent-solute interactions on the c...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...
Solvent effects on O-H stretching vibration frequency of methanol in hydrogen bond complexes with di...