Add to ORKGThe synthesis of N-(1-halo-2-alkylidene)amines, i.e. alpha-halomethyl ketimines, is described for the first time, utilizing the TiCl4-induced condensation of alpha-halomethyl ketones with primary amines. The reactivity of these new alpha-halomethyl ketimines was studied with respect to nucleophiles such as iodide, cyanide, alcohols, alkoxides, amines and thiolates. Alpha-halomethyl ketimines are powerful ambident electrophiles which underwent a variety of reactions leading to functionalized imines and heterocycles
A TiCl4-mediated reaction for the direct amination of alpha-hydroxy amides has been developed. This ...
In this thesis, methodology developments for the synthesis of cyclic imines employing a series of al...
alpha-Halomethyllithium carbenoids are useful homologating reagents which - reacting under proper re...
The synthesis of N-(1-halo-2-alkylidene)amines, i.e. alpha-halomethyl ketimines, is described for th...
A variety of different N-(2,2,3-trichloropropylidene)amines, N-(2,2,3-trichlorobutylidene)amines, ...
A variety of different N-(2,2,3-trichloropropylidene)amines, N-(2,2,3-trichlorobutylidene)amines,...
A variety of different N-(2,2,3-trichloropropylidene)amines, N-(2,2,3-trichlorobutylidene)amines,...
The direct synthesis of ketimines from ammonia and ketones catalyzed by ammonium chloride is describ...
An efficient and modular entry to alpha-halogenated amides and esters is reported. This reaction is ...
We started our study by preparation two ketoximes. Later, there were studies to reveal these ketoxim...
A new reactivity mode of hindered lithium amides with terminal epoxides is described whereby aldehyd...
A novel synthesis of 1,4-dialkyl-5-aryl-4-imidazolin-2-ones 3 has been achieved by reaction of alpha...
A TiCl4-mediated reaction for the direct amination of alpha-hydroxy amides has been developed. This ...
To avoid the undesired deprotonation during the addition of organolithium and organomagnesium reagen...
Disubstituted-alpha-chloroenamines are useful synthetic intermediates which bad earlier been prepare...
A TiCl4-mediated reaction for the direct amination of alpha-hydroxy amides has been developed. This ...
In this thesis, methodology developments for the synthesis of cyclic imines employing a series of al...
alpha-Halomethyllithium carbenoids are useful homologating reagents which - reacting under proper re...
The synthesis of N-(1-halo-2-alkylidene)amines, i.e. alpha-halomethyl ketimines, is described for th...
A variety of different N-(2,2,3-trichloropropylidene)amines, N-(2,2,3-trichlorobutylidene)amines, ...
A variety of different N-(2,2,3-trichloropropylidene)amines, N-(2,2,3-trichlorobutylidene)amines,...
A variety of different N-(2,2,3-trichloropropylidene)amines, N-(2,2,3-trichlorobutylidene)amines,...
The direct synthesis of ketimines from ammonia and ketones catalyzed by ammonium chloride is describ...
An efficient and modular entry to alpha-halogenated amides and esters is reported. This reaction is ...
We started our study by preparation two ketoximes. Later, there were studies to reveal these ketoxim...
A new reactivity mode of hindered lithium amides with terminal epoxides is described whereby aldehyd...
A novel synthesis of 1,4-dialkyl-5-aryl-4-imidazolin-2-ones 3 has been achieved by reaction of alpha...
A TiCl4-mediated reaction for the direct amination of alpha-hydroxy amides has been developed. This ...
To avoid the undesired deprotonation during the addition of organolithium and organomagnesium reagen...
Disubstituted-alpha-chloroenamines are useful synthetic intermediates which bad earlier been prepare...
A TiCl4-mediated reaction for the direct amination of alpha-hydroxy amides has been developed. This ...
In this thesis, methodology developments for the synthesis of cyclic imines employing a series of al...
alpha-Halomethyllithium carbenoids are useful homologating reagents which - reacting under proper re...