A single-event microkinetic (SEMK) model was developed for Fischer-Tropsch synthesis and applied to experimental data obtained on an iron-based catalyst in a temperature range from 523 to 623 K, total pressures from 0.6 to 2.1 MPa, and H-2/CO inlet ratios from 2 to 6 mol/mol. The use of the single-event concept allowed a significant reduction of the number of adjustable parameters. The single-event pre-exponential factors were calculated based on statistical thermodynamics. The reaction enthalpies, as well as initial guesses for the activation energies, were obtained through the unity bond index-quadratic exponential potential (UBI-QEP) method. Ten activation energies of the kinetically relevant reaction families and four atomic chemisorpti...
Experiments for the kinetic of Fischer-Tropsch reaction (hydrocarbon formation) have been carried ...
In this work, a wall-cooled fixed-bed reactor was simulated using a 1-D heterogeneous model for Fisc...
This report covers the third year of this research grant under the University Coal Research program....
A single-event microkinetic (SEMK) model was developed for Fischer-Tropsch synthesis and applied to ...
The construction of a single-event microkinetic (SEMK) model for metal catalysis using Fischer-Trops...
Kinetic models constitute a useful tool to provide fundamental insights for catalyst development. Si...
AbstractThe microkinetic of gas-solid Fischer-Tropsch synthesis on Fe–Cu–K–SiO2 catalyst was studied...
Extension of the Single-Event Methodology to Metal Catalysis: Application to Fischer-Tropsch Synthes...
A Single-Event MicroKinetic (SEMK) model has been extended towards the simulation of Steady StateIso...
Fischer-Tropsch (FT) synthesis was carried out in a microchannel reactor using an iron based catalys...
The kinetic models of Fischer-Tropsch synthesis (FTS) product distribution can be classified into tw...
Efforts during this second year focused on four areas: (1) continued searching and summarizing of pu...
AbstractThe Fischer Tropsch (FT) synthesis is a complex polymerization reaction characterized by com...
The Fischer-Tropsch (FT) synthesis provides a method of converting syngas, obtained from the gasific...
Microkinetics simulations are presented based on DFT-determined elementary reaction steps of the Fis...
Experiments for the kinetic of Fischer-Tropsch reaction (hydrocarbon formation) have been carried ...
In this work, a wall-cooled fixed-bed reactor was simulated using a 1-D heterogeneous model for Fisc...
This report covers the third year of this research grant under the University Coal Research program....
A single-event microkinetic (SEMK) model was developed for Fischer-Tropsch synthesis and applied to ...
The construction of a single-event microkinetic (SEMK) model for metal catalysis using Fischer-Trops...
Kinetic models constitute a useful tool to provide fundamental insights for catalyst development. Si...
AbstractThe microkinetic of gas-solid Fischer-Tropsch synthesis on Fe–Cu–K–SiO2 catalyst was studied...
Extension of the Single-Event Methodology to Metal Catalysis: Application to Fischer-Tropsch Synthes...
A Single-Event MicroKinetic (SEMK) model has been extended towards the simulation of Steady StateIso...
Fischer-Tropsch (FT) synthesis was carried out in a microchannel reactor using an iron based catalys...
The kinetic models of Fischer-Tropsch synthesis (FTS) product distribution can be classified into tw...
Efforts during this second year focused on four areas: (1) continued searching and summarizing of pu...
AbstractThe Fischer Tropsch (FT) synthesis is a complex polymerization reaction characterized by com...
The Fischer-Tropsch (FT) synthesis provides a method of converting syngas, obtained from the gasific...
Microkinetics simulations are presented based on DFT-determined elementary reaction steps of the Fis...
Experiments for the kinetic of Fischer-Tropsch reaction (hydrocarbon formation) have been carried ...
In this work, a wall-cooled fixed-bed reactor was simulated using a 1-D heterogeneous model for Fisc...
This report covers the third year of this research grant under the University Coal Research program....