Mechanism-based design of labile precursors for chromium(I) chemistry
- Akturk, Eser S.
- Yap, Glenn P. A.
- Theopold, Klaus H.
Publication date
August 2015
DOI Publisher
Royal Society of Chemistry ISSN
1359-7345 Citation count (estimate)
2Abstract
Final published version.Dinitrogen complexes of the type TpR,RCr???N2???CrTpR,R are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex ??? TptBu,MeCr(g2-C2(SiMe3)2) ??? proved to be much more reactive.University of Delaware. Department of Chemistry and Biochemistry
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