We present a new method for classifying naturally reductive homogeneous spaces – i.e.homogeneous Riemannian manifolds admitting a metric connection with skew torsion that has parallel torsion and curvature. This method is based on a deeper understanding of the holonomy algebra of connections with parallel skew torsion on Riemannian manifolds and the interplay of such a connection with the geometric structure on the given Riemannian manifold. It allows to reproduce by easier arguments the known classifications in dimensions 3, 4, and 5, and yields as a new result the classification in dimension 6. In each dimension, one obtains a ‘hierarchy’ of degeneracy for the torsion form, which we then treat case by case. For the completely degenerate c...