Noncovalent interactions involving metals as electron acceptors are continuously under investigation. The term “matere bond” has been proposed to identify noncovalent donor–acceptor interactions where elements of group 7 of the periodic table play the role of the electrophilic site. Most of the works on matere bonds involve rhenium atoms usually in +7 oxidation state. This work emphasizes for the first time their importance in technetium derivatives in several oxidation states (+7, +6, +5, and +3). The Cambridge Structural Database (CSD) in combination with density functional theory (DFT) calculations are used to demonstrate the structure directing role of matere bonds in X-ray structures, even involving anion⋯anion interactions. Further ch...
A computational study of the interaction half-sandwich metal fragments (metal=Re/W, electron count=d...
<div><p>We report a theoretical study of a series of Ru complexes of interest in dye-sensitised sola...
In the last few years. the quantum theory of atoms in molecules has become the paradigm for interpre...
The metal–metal bond is central in the chemistry of polymetallic complexes. Many structural investig...
In this communication experimental and theoretical results are reported affording strong evidence th...
This is a study of certain aspects of the chemistry of low valency states of the two group VIIa elem...
In this thesis investigations on the structure and chemical bonding in some organometallic compounds...
Three sets of metal-metal bonded systems of the form M₂(L ͡ L)₄ have been studied by gas-phase ultra...
© 2020 by the authors.In this review, we provide a consistent description of noncovalent interaction...
: Analyses of the Cambridge Structural Database and theoretical calculations (PBE0-D3/def2-TZVP leve...
The nature of multiple bonding involving transition metal atoms has been explored via photoelectron ...
Computational methods were used to analyse the interactions around the metal centres in three trans...
The equilibrium geometries and bond-dissociation energies for loss of one CO and loss of six CO from...
In this thesis, compounds with potential triple-bonding character involving the heavier main-group e...
The study of metal–metal bonds is one of the important challenges in organometallic chemistry and of...
A computational study of the interaction half-sandwich metal fragments (metal=Re/W, electron count=d...
<div><p>We report a theoretical study of a series of Ru complexes of interest in dye-sensitised sola...
In the last few years. the quantum theory of atoms in molecules has become the paradigm for interpre...
The metal–metal bond is central in the chemistry of polymetallic complexes. Many structural investig...
In this communication experimental and theoretical results are reported affording strong evidence th...
This is a study of certain aspects of the chemistry of low valency states of the two group VIIa elem...
In this thesis investigations on the structure and chemical bonding in some organometallic compounds...
Three sets of metal-metal bonded systems of the form M₂(L ͡ L)₄ have been studied by gas-phase ultra...
© 2020 by the authors.In this review, we provide a consistent description of noncovalent interaction...
: Analyses of the Cambridge Structural Database and theoretical calculations (PBE0-D3/def2-TZVP leve...
The nature of multiple bonding involving transition metal atoms has been explored via photoelectron ...
Computational methods were used to analyse the interactions around the metal centres in three trans...
The equilibrium geometries and bond-dissociation energies for loss of one CO and loss of six CO from...
In this thesis, compounds with potential triple-bonding character involving the heavier main-group e...
The study of metal–metal bonds is one of the important challenges in organometallic chemistry and of...
A computational study of the interaction half-sandwich metal fragments (metal=Re/W, electron count=d...
<div><p>We report a theoretical study of a series of Ru complexes of interest in dye-sensitised sola...
In the last few years. the quantum theory of atoms in molecules has become the paradigm for interpre...