Assessing the sequestration time scales of some ocean-based carbon dioxide reduction strategies

© The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Siegel, D. A., DeVries, T., Doney, S. C., & Bell, T. W. Assessing the sequestration time scales of some ocean-based carbon dioxide reduction strategies. Environmental Research Letters, 16(10), (2021): 104003, https://doi.org/10.1088/1748-9326/ac0be0.Ocean-based carbon dioxide (CO2) removal (CDR) strategies are an important part of the portfolio of approaches needed to achieve negative greenhouse gas emissions. Many ocean-based CDR strategies rely on injecting CO2 or organic carbon (that will eventually become CO2) into the ocean interior, or enhancing the ocean's biological pump. These approaches will not result in permanent sequestration, because ocean currents will eventually return the injected CO2 back to the surface, where it will be brought into equilibrium with the atmosphere. Here, a model of steady state global ocean circulation and mixing is used to assess the time scales over which CO2 injected in the ocean interior remains sequestered from the atmosphere. There will be a distribution of sequestration times for any single discharge location due to the infinite number of pathways connecting a location at depth with the sea surface. The resulting probability distribution is highly skewed with a long tail of very long transit times, making mean sequestration times much longer than typical time scales. Deeper discharge locations will sequester purposefully injected CO2 much longer than shallower ones and median sequestration times are typically decades to centuries, and approach 1000 years in the deep North Pacific. Large differences in sequestration times occur both within and between the major ocean basins, with the Pacific and Indian basins generally having longer sequestration times than the Atlantic and Southern Oceans. Assessments made over a 50 year time horizon illustrates that most of the injected carbon will be retained for injection depths greater than 1000 m, with several geographic exceptions such as the Western North Atlantic. Ocean CDR strategies that increase upper ocean ecosystem productivity with the goal of exporting more carbon to depth will have mainly a short-term influence on atmospheric CO2 levels because ∼70% will be transported back to the surface ocean within 50 years. The results presented here will help plan appropriate ocean CDR strategies that can help limit climate damage caused by fossil fuel CO2 emissions.D A S acknowledges support from NASA Grant 80NSSC17K0692. D A S and T B acknowledge support from US Department of Energy's Advanced Research Projects Agency–Energy cooperative Agreement DE-AR0000922. T D acknowledges support from NSF Grant OCE-1948955. S C D acknowledges support from the University of Virginia Environmental Resilience Institute