The first tricyclic [12]annulene with an unsubstituted perimeter, namely the blue hydrocarbon 2, could be prepared from the azulene derivative 1. Compound 2 proved to be an antiaromatic 12π-electron system par excellence
Cycloadditions to the azulene system have not hitherto been observed. Instead, azulene reacts, e.g.,...
Reaction of dimethyl acetylenedicarboxylate 2a with azulene 1 (boiling tetralin, 207.6 °C) leads to ...
ABSTRACT: Novel azulene building blocks, prepared via the cycloaddition of thiophene-S,S-dioxides an...
The first tricyclic [12]annulene with an unsubstituted perimeter, namely the blue hydrocarbon 2, cou...
Methyl derivatives of the still unknown hydrocarbon (1a) azuleno[8,8a,1,2-def]heptalene (dicyclohept...
Cycloaddition reactions of the azulene system 1 with electron-poor and electron-rich alkynes provide...
The non-benzenoid aromatic system azulene is sufficiently nucleophilic at C1 that it can react with ...
Cycloadditions of nonbenzenoid carbo- and heterocyclic conjugated π-electron systems with suitable ...
It is shown, on the example of the monocyclic cyclononatetraenyl cation, C9H9+, that the fully-varia...
s-Indacenes reveal the limits of the Hückel rules: These 12π systems are formally antiaromatic, but ...
A conformational Study of the energies and geometries of two di-benzo [10]-annulenes, their methylat...
Like acenaphthylene (1), the isomeric compound cyclopent- [cd]azulene (2) can also undergo 1,2-cyclo...
Pang Sik Wing.Thesis (M.Phil.)--Chinese University of Hong Kong, 1979.Bibliography: leaves 70-73.Ack...
A completely planar, delocalized 14π-electron system which does not contain cyclically conjugated su...
The question of the nature of bonding in pentalene (1) has motivated numerous experimental and theo...
Cycloadditions to the azulene system have not hitherto been observed. Instead, azulene reacts, e.g.,...
Reaction of dimethyl acetylenedicarboxylate 2a with azulene 1 (boiling tetralin, 207.6 °C) leads to ...
ABSTRACT: Novel azulene building blocks, prepared via the cycloaddition of thiophene-S,S-dioxides an...
The first tricyclic [12]annulene with an unsubstituted perimeter, namely the blue hydrocarbon 2, cou...
Methyl derivatives of the still unknown hydrocarbon (1a) azuleno[8,8a,1,2-def]heptalene (dicyclohept...
Cycloaddition reactions of the azulene system 1 with electron-poor and electron-rich alkynes provide...
The non-benzenoid aromatic system azulene is sufficiently nucleophilic at C1 that it can react with ...
Cycloadditions of nonbenzenoid carbo- and heterocyclic conjugated π-electron systems with suitable ...
It is shown, on the example of the monocyclic cyclononatetraenyl cation, C9H9+, that the fully-varia...
s-Indacenes reveal the limits of the Hückel rules: These 12π systems are formally antiaromatic, but ...
A conformational Study of the energies and geometries of two di-benzo [10]-annulenes, their methylat...
Like acenaphthylene (1), the isomeric compound cyclopent- [cd]azulene (2) can also undergo 1,2-cyclo...
Pang Sik Wing.Thesis (M.Phil.)--Chinese University of Hong Kong, 1979.Bibliography: leaves 70-73.Ack...
A completely planar, delocalized 14π-electron system which does not contain cyclically conjugated su...
The question of the nature of bonding in pentalene (1) has motivated numerous experimental and theo...
Cycloadditions to the azulene system have not hitherto been observed. Instead, azulene reacts, e.g.,...
Reaction of dimethyl acetylenedicarboxylate 2a with azulene 1 (boiling tetralin, 207.6 °C) leads to ...
ABSTRACT: Novel azulene building blocks, prepared via the cycloaddition of thiophene-S,S-dioxides an...