Fingerprints of Frontal Passages and Post-Depositional Effects in the Stable Water Isotope Signal of Seasonal Alpine Snow

Stable water isotopes are used as a paleothermometer in ice cores for climate reconstructions over the past millennia. The underlying physical processes involved in the isotope-temperature relation, however, unfold at much shorter timescales. Here, we study the temporary archival of frontal passages in the seasonal Alpine snow cover. We combine five snow profiles sampled in winter 2017 at the Weissfluhjoch with a quantitative snow layer age reconstruction and atmospheric reanalysis data to characterize the circulation and clouds associated with the precipitation producing synoptic-scale cold and warm fronts. We find that the vertical cloud structure and the air parcels' net cooling during transport leave a distinct imprint in the delta O-18 and delta D vertical profile in the snow. The near-surface humidity gradient at the moisture source is reflected in the second order isotope parameter deuterium excess. In the cold season, these environmental conditions during cloud formation and at the moisture source are preserved in the snow. In the melt season, significant post-depositional effects due to wet snow metamorphism, however, leads to an enrichment in heavy isotopes in the snow and a strong smoothing of the initial atmospheric imprint. These findings show that the isotope signal archived in the dry snow cover is strongly modulated by individual weather systems prior to deposition. Major shifts in the upper-level jet stream and cyclone tracks likely leading to changes in moisture source regions and conditions, could therefore be detectable in the isotope composition of Alpine ice