Thiolate-protected Au144 nanoclusters (NCs) are an intriguing member of the gold NC family. Their geometric structure, distinct electrochemical features, and susceptibility to structural rearrangement under the duress of ligand exchange have been studied. However, there are currently no established protocols for surface modification or tuning of their ligand shells post synthesis. Here, the direct synthesis of three regioisomers of azide-modified Au144 NCs with 60 azide moieties, i.e., Au144(SC2H4C6H4-N3)60, is reported, in which the azide functionality is located at the ortho-, meta-, or para position of the ligand’s phenyl ring. The regioisomeric effect of the azide group on Au144(SC2H4C6H4-N3)60 synthesis and physical properties are desc...
The glutathione-mediated, retro Michael-type addition reaction is demonstrated to take place at the ...
AbstractThis Letter reports on the synthesis of Ag–Au nanoparticles (NPs) with controlled structures...
We report on the conjugation of azide-derivatized gold nanoparticles (AuNPs) to alkyne moieties of Z...
Azide-functionalized [Au25(SR)18] gold nanoclusters [Au25(SCH2CH2C6H4-N3)18]- are able to undergo po...
This thesis explores the preparation of thiolated gold nanoparticles (AuNPs) and thiolated gold nano...
Ultrasmall atomically precise monolayer-protected gold thiolate nanoclusters are an intensely resear...
In nanocluster research, easy modification of the cluster surface while maintaining the cluster core...
This thesis describes the development of bioorthogonal chemical tools — originally designed to form ...
Protective ligands are key components of ligand-protected metal nanoclusters (NCs), as they offer g...
Atom-precise water-soluble amine-terminated Au nanoclusters (NCs) with various core sizes have been ...
Gold nanomolecules are atomically monodisperse nano-particles having a precise number of gold atoms ...
Immobilization of different bio- and organic molecules on solid supports is fundamental within many ...
In the past few years, the interest in the study of atomically precise metal nanoclusters has grown ...
AbstractA trio of thiolate-protected atomically precise gold nanoclusters, [Au23(S-c-C6H11)16]–, Au2...
Metal nanoclusters (MNCs) emerged a massive interest due to their size-tunable photochemical propert...
The glutathione-mediated, retro Michael-type addition reaction is demonstrated to take place at the ...
AbstractThis Letter reports on the synthesis of Ag–Au nanoparticles (NPs) with controlled structures...
We report on the conjugation of azide-derivatized gold nanoparticles (AuNPs) to alkyne moieties of Z...
Azide-functionalized [Au25(SR)18] gold nanoclusters [Au25(SCH2CH2C6H4-N3)18]- are able to undergo po...
This thesis explores the preparation of thiolated gold nanoparticles (AuNPs) and thiolated gold nano...
Ultrasmall atomically precise monolayer-protected gold thiolate nanoclusters are an intensely resear...
In nanocluster research, easy modification of the cluster surface while maintaining the cluster core...
This thesis describes the development of bioorthogonal chemical tools — originally designed to form ...
Protective ligands are key components of ligand-protected metal nanoclusters (NCs), as they offer g...
Atom-precise water-soluble amine-terminated Au nanoclusters (NCs) with various core sizes have been ...
Gold nanomolecules are atomically monodisperse nano-particles having a precise number of gold atoms ...
Immobilization of different bio- and organic molecules on solid supports is fundamental within many ...
In the past few years, the interest in the study of atomically precise metal nanoclusters has grown ...
AbstractA trio of thiolate-protected atomically precise gold nanoclusters, [Au23(S-c-C6H11)16]–, Au2...
Metal nanoclusters (MNCs) emerged a massive interest due to their size-tunable photochemical propert...
The glutathione-mediated, retro Michael-type addition reaction is demonstrated to take place at the ...
AbstractThis Letter reports on the synthesis of Ag–Au nanoparticles (NPs) with controlled structures...
We report on the conjugation of azide-derivatized gold nanoparticles (AuNPs) to alkyne moieties of Z...