A Modelling Study of Post-Combustion Capture Plant Process Conditions to Facilitate 95–99% CO<inf>2</inf> Capture Levels From Gas Turbine Flue Gases

The principal purpose of this study is to examine the changes in process conditions that might be needed to achieve up to 99% capture levels in amine post-combustion capture (PCC) plants for combined cycle gas turbine (CCGT) flue gases. This information is of interest since, while 95% capture is adequate for current market and regulatory conditions, net zero fossil emissions (99% capture for a CCGT plant) will be required to deliver global climate mitigation targets and is increasingly a target for national climate policies. The conventionally-configured plant in the study is based on FEED studies carried out by Bechtel Corporation and uses MEA at 35% w/w. Performance modelling is undertaken using the Aspen Plus CCSI MEA Steady State Model. The results show that efficient operation at higher capture levels appears to be feasible with minimal adjustments to the plant configuration, provided that the absorber has a sufficient packing height and the stripper is capable of operation at pressures above 2 bar. The study primarily focuses on operation at low lean loadings (0.09–0.15 molCO2/molMEA) and correspondingly low L/G ratios (