The total internal partition function of methane is revisited to provide reliable values at high temperature. A multi-resolution approach is used to perform a direct summation over all the rovibrational energy levels up to the dissociation limit. A computer code is executable on line at the URL : http://icb.u-bourgogne.fr/JSP/TIPS.jsp to allow the calculation of the partition sum of methane at temperatures up to 3000 K. It also provides detailed information on the density of states in the relevant spectral ranges. The recommended values include uncertainty estimates. It is shown that at the upper limit of 3000 K, the systematic error (underestimation) of previous calculations (HITRAN 2004) reaches -50\% equivalent to a temperature error of ...
La version V2 inclut les modifications proposées par les reviewers.International audienceA general m...
International audienceAstrophysical investigations generally need both complete and accurate spectro...
We have recorded laboratory high resolution Fourier transform spectra of methane (CH4) emission at 8...
11 pages, 4 Tables, 3 Figures Computer code on line at http://icb.u-bourgogne.fr/JSP/TIPS.jspInterna...
The temperature dependence of the methane 12CH4 partition function was investigated up to T=3000 K. ...
Author Institution: The Center for Atmospheric Research, The University of Lowell; Optics Division, ...
International audienceRemote sensing of the atmosphere of astrophysical objects relies essentially o...
Author Institution: Department of Chemistry, University of WaterlooAbsorption bands from hot methane...
The rovibration partition function of CH4 was calculated in the temperature range of 100-1000 K usin...
International audienceA high-enthalpy source (HES) has been developed in Rennes either to heat gases...
Spectra of hot methane were recorded using a tube furnace and a high-resolution Fourier transform sp...
Infrared absorption spectra of hot methane up to 1000 K were recorded with a high-resolution Fourier...
Methane plays a central role in gas layers of temperatures up to around 3000 K in a number of astrop...
Hot methane is found in many cool sub-stellar astronomical sources including brown dwarfs and exop...
Astrophysical investigations generally need both complete and accurate spectroscopic databases. Desp...
La version V2 inclut les modifications proposées par les reviewers.International audienceA general m...
International audienceAstrophysical investigations generally need both complete and accurate spectro...
We have recorded laboratory high resolution Fourier transform spectra of methane (CH4) emission at 8...
11 pages, 4 Tables, 3 Figures Computer code on line at http://icb.u-bourgogne.fr/JSP/TIPS.jspInterna...
The temperature dependence of the methane 12CH4 partition function was investigated up to T=3000 K. ...
Author Institution: The Center for Atmospheric Research, The University of Lowell; Optics Division, ...
International audienceRemote sensing of the atmosphere of astrophysical objects relies essentially o...
Author Institution: Department of Chemistry, University of WaterlooAbsorption bands from hot methane...
The rovibration partition function of CH4 was calculated in the temperature range of 100-1000 K usin...
International audienceA high-enthalpy source (HES) has been developed in Rennes either to heat gases...
Spectra of hot methane were recorded using a tube furnace and a high-resolution Fourier transform sp...
Infrared absorption spectra of hot methane up to 1000 K were recorded with a high-resolution Fourier...
Methane plays a central role in gas layers of temperatures up to around 3000 K in a number of astrop...
Hot methane is found in many cool sub-stellar astronomical sources including brown dwarfs and exop...
Astrophysical investigations generally need both complete and accurate spectroscopic databases. Desp...
La version V2 inclut les modifications proposées par les reviewers.International audienceA general m...
International audienceAstrophysical investigations generally need both complete and accurate spectro...
We have recorded laboratory high resolution Fourier transform spectra of methane (CH4) emission at 8...