Add to ORKGA family of pyridine dipyrrolide bismuth complexes (Mes,PhL)MX (1–6) (M = Bi, X = O-2,6-Me-C6H3 = OXyl (1); M = Sb, X = OXyl (2); M = Bi, X = O-2,6-iPr-C6H3 = ODipp (3), O-2,6-tBu-C6H3 = OArtBu (4), OtBu (5) and OCMe2Et = OAm (6), N(SiMe3)2 = N′′ (7) and CH2Ph (8)) have been prepared and investigated as initiators for the ring-opening polymerisation of lactide monomers. Bismuth lactate complexes (Mes,PhL)Bi{OC(H)(Me)C([double bond, length as m-dash]O)OR} were prepared as models for the propagating species (R = tBu (9), Me (10), iPr (11)). The first insertion of the lactide monomer is rate limiting and the second and subsequent insertions are more rapid (kinit ≪ kLA2 < kprop), leading to a significant induction period. The sterically demandi...
On the long road of tridentate bis(pyrazolyl)methane ligand and complex design, this thesis goes one...
A series of Schiff-base compounds containing bimetallic ligands and two aluminum centers have been s...
The main objective of the present work is the investigation of the ring-opening polymerization (ROP)...
We report the synthesis of new hexadentate ligands bearing imine and pyridine nitrogen neutral dono...
We report the synthesis of new hexadentate ligands bearing imine and pyridine nitrogen neutral dono...
We report the synthesis of new hexadentate ligands bearing imine and pyridine nitrogen neutral dono...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
Reaction of LnCl<sub>3</sub> (Ln = Y, Yb) with 2 equiv of NaL<sup>2,6‑ipr2</sup><sub>Ph</sub> (L<sup...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
Four bismuth complexes, (H 2En)[Bi 2(cit) 2(H 2O) 4/3]•(H 2O) x (1), (H 2En) 3[Bi 2(cit) 2Cl 4]•(H 2...
A series of well-defined group 4 permethylindenyl complexes have been prepared and fully characteris...
The reaction of MgBu2 and ZnEt2 or Zn{N[Si(CH3)3]2}2 with a tridentate monoanionic pyrrolylpyridiyli...
The reaction of MgBu2 and ZnEt2 or Zn{N[Si(CH3)3]2}2 with a tridentate monoanionic pyrrolylpyridiyli...
On the long road of tridentate bis(pyrazolyl)methane ligand and complex design, this thesis goes one...
A series of Schiff-base compounds containing bimetallic ligands and two aluminum centers have been s...
The main objective of the present work is the investigation of the ring-opening polymerization (ROP)...
We report the synthesis of new hexadentate ligands bearing imine and pyridine nitrogen neutral dono...
We report the synthesis of new hexadentate ligands bearing imine and pyridine nitrogen neutral dono...
We report the synthesis of new hexadentate ligands bearing imine and pyridine nitrogen neutral dono...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
Reaction of LnCl<sub>3</sub> (Ln = Y, Yb) with 2 equiv of NaL<sup>2,6‑ipr2</sup><sub>Ph</sub> (L<sup...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
The reaction of one equivalent of dilithiated O(SiMe2-Ap-H)(2) [Ap-H = -N(2-amino-4-methylpyridine)]...
Four bismuth complexes, (H 2En)[Bi 2(cit) 2(H 2O) 4/3]•(H 2O) x (1), (H 2En) 3[Bi 2(cit) 2Cl 4]•(H 2...
A series of well-defined group 4 permethylindenyl complexes have been prepared and fully characteris...
The reaction of MgBu2 and ZnEt2 or Zn{N[Si(CH3)3]2}2 with a tridentate monoanionic pyrrolylpyridiyli...
The reaction of MgBu2 and ZnEt2 or Zn{N[Si(CH3)3]2}2 with a tridentate monoanionic pyrrolylpyridiyli...
On the long road of tridentate bis(pyrazolyl)methane ligand and complex design, this thesis goes one...
A series of Schiff-base compounds containing bimetallic ligands and two aluminum centers have been s...
The main objective of the present work is the investigation of the ring-opening polymerization (ROP)...