Online Identification of VLRA Battery Model Parameters Using Electrochemical Impedance Spectroscopy

This paper introduces the use of a new low-computation cost algorithm combining neural networks with the Nelder–Mead simplex method to monitor the variations of the parameters of a previously selected equivalent circuit calculated from Electrochemical Impedance Spectroscopy (EIS) corresponding to a series of battery aging experiments. These variations could be correlated with variations in the battery state over time and, therefore, identify or predict battery degradation patterns or failure modes. The authors have benchmarked four different Electrical Equivalent Circuit (EEC) parameter identification algorithms: plain neural network mapping EIS raw data to EEC parameters, Particle Swarm Optimization, Zview, and the proposed new one. In order to improve the prediction accuracy of the neural network, a data augmentation method has been proposed to improve the neural network training error. The proposed parameter identification algorithms have been compared and validated through real data obtained from a six-month aging test experiment carried out with a set of six commercial 80 Ah VLRA batteries under different cycling and temperature operation conditions