Morphology Control of PbZr_xTi_1-xO₃ Crystallites under Alkaline Hydrothermal Conditions

Outstanding ferroelectric and piezoelectric properties of PbZrxTi1-xO3 (PZT) make nano and sub-micrometer particles of this material interesting for future nanotechnological applications as well as for fundamental studies of ferroelectricity at the nanoscale. In the present work, the prospects of a new hydrothermal approach were explored to control the particle size, aggregation stage, and composition of the PZT with the target composition of Zr/Ti = 60/40 (x = 0.6). Starting with water-soluble Zr-, Ti-, and Pb-precursors, the PZT formation was examined in the broad base (KOH) concentration range. The PZT particle size and composition were governed by the ratio of KOH with respect to Pb and not by the absolute KOH concentration (cKOH). The incorporation of Zr into the PZT perovskite phase began to decline at KOH:Pb ≤ 1.7 and at KOH:Pb > 20. In the concentration range of 20 ≥ KOH:Pb > 1.5, the PZT particles adopted a cube-like shape, the size of which decreased with a decrease in the KOH:Pb ratio. The smallest (