Globally, excess soil nutrient mining is a serious challenge to sustainable agricultural production. The task is more daunting in the semi-arid region of the globe. In addition to the primary nutrient deficiency over the mining of secondary nutrients, especially sulfur is an emerging challenge in contemporary crop production systems. Hence, there is a dire need to devise an appropriate sulfur management protocol by searching for efficient and sustainable sulfur sources. Therefore, the efficacy of new sulfur molecules was evaluated on the performance and nutrient acquisition potential of the pearl millet–mustard system at the research farm of the Indian Agricultural Research Institute in New Delhi, India, for two years. The flexibility of ur...