Generating Triple Crystalline Superstructures in Melt Miscible PEO-b-PCL-b-PLLA Triblock Terpolymers by Controlling Thermal History and Sequential Crystallization

The morphology, crystallization behavior and properties of multi-crystalline polymer systems based on triple crystalline biodegradable PEO-b-PCL-b-PLLA triblock terpolymers are reviewed. The triblock terpolymers, with increasing PLLA content, exhibited a triple crystalline nature. Upon cooling from melt, the PLLA block crystallizes first and templates the spherulitic morphology of the terpolymer. Then, the PCL block crystalizes and, lastly, the PEO block. These triblock terpolymers are probably melt miscible, as SAXS experiments confirmed. Thus, the crystallization of PCL and PEO blocks takes place within the interlamellar zones of the PLLA spherulites that were formed previously. Therefore, the lamellae of PLLA, PCL and PEO exist side-by-side within a unique spherulite, constituting a novel triple crystalline superstructure. The theoretical analysis of SAXS curves implies that only one lamella of either PCL or PEO can occupy the interlamellar space in between two contiguous lamellae of PLLA. Several complex competitive effects such as plasticizing, nucleation, anti-plasticizing and confinement take place during the isothermal crystallization of each block in the terpolymers. New results on how Successive Self-nucleation and Annealing (SSA) thermal treatment can be used as an additional suitable technique to properly separate the three crystalline phases in these triple crystalline triblock terpolymers are also included in this contribution.The POLYMAT/UPV/EHU team would like to acknowledge funding from MINECO through project: MAT2017-83014-C2-1-P, and from ALBA synchrotron facility. We also acknowledge funding by the European Union´s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 778092. The support of the National Key R&D Program of China (2017YFE0117800) is also gratefully acknowledged