Capability of the Direct Dimethyl Ether Synthesis Process for tCapability of the Direct Dimethyl Ether Synthesis Process for the Conversion of Carbon Dioxide

The direct synthesis of dimethyl ether (DME) is an ideal process to achieve the environmental objective of CO2 conversion together with the economic objective of DME production. The effect of the reaction conditions (temperature, pressure, space time) and feed composition (ternary mixtures of H-2 + CO + CO2 with different CO2/CO and H-2/COX molar ratios) on the reaction indices (COX conversion, product yield and selectivity, CO2 conversion) has been studied by means of experiments carried out in a fixed-bed reactor, with a CuO-ZnO-MnO/SAPO-18 catalyst, in order to establish suitable ranges of operating conditions for enhancing the individual objectives of CO2 conversion and DME yield. The optimums of these two objectives are achieved in opposite conditions, and for striking a good balance between both objectives, the following conditions are suitable: 275-300 degrees C; 20-30 bar; 2.5-5 g(cat) h (mol(C))(-1) and a H-2/COX molar ratio in the feed of 3. CO2/CO molar ratio in the feed is of great importance. Ratios below 1/3 are suitable for enhancing DME production, whereas CO2/CO ratios above 1 improve the conversion of CO2. This conversion of CO2 in the overall process of DME synthesis is favored by the reverse water gas shift equation, since CO is more active than CO2 in the methanol synthesis reaction.This work has been carried out with the financial support of the Ministry of Economy and Competitiveness of the Spanish Government (CTQ2013-46173-R), the FEDER funds, the Basque Government (Project IT748-13). Ainara Ateka and Miguel Sanchez-Contador are grateful for the Ph.D. grants from the Department of Education, University and Research of the Basque Government (BFI09.69 and PRE_2013_1_841, respectively)