Micro-Capillary Coatings Based on Spiropyran Polymeric Brushes for Metal Ion Binding, Detection, and Release in Continuous Flow

Micro-capillaries, capable of light-regulated binding and qualitative detection of divalent metal ions in continuous flow, have been realised through functionalisation with spiropyran photochromic brush-type coatings. Upon irradiation with UV light, the coating switches from the passive non-binding spiropyran form to the active merocyanine form, which binds different divalent metal ions (Zn2+, Co2+, Cu2+, Ni2+, Cd2+), as they pass through the micro-capillary. Furthermore, the merocyanine visible absorbance spectrum changes upon metal ion binding, enabling the ion uptake to be detected optically. Irradiation with white light causes reversion of the merocyanine to the passive spiropyran form, with simultaneous release of the bound metal ion from the micro-capillary coating.This project has been funded by Science Foundation Ireland under the Insight initiative, grant SFI/12/RC/2289. C.D. and D.D. also acknowledge the SFI under the Technology Innovation Development Award no. 16/TIDA/4183. F.B.L. acknowledges the Ramon y Cajal Programme (Ministerio de Economia y Competitividad) and Gobierno de Espana, Ministerio de Economia y Competitividad, with Grant No. BIO2016-80417-P