Time-dependent electron phenomena at surfaces

6 pages, 5 figures.-- Published online before print November 22, 2010.-- Full-text available Open Access at the publisher's site.Femtosecond and subfemtosecond time scales typically rule electron dynamics at metal surfaces. Recent advance in experimental techniques permits now remarkable precision in the description of these processes. In particular, shorter time scales, smaller system sizes, and spin-dependent effects are current targets of interest. In this article, we use state-of-the-art theoretical methods to analyze these refined features of electron dynamics. We show that the screening of localized charges at metal surfaces is created locally in the attosecond time scale, while collective excitations transfer the perturbation to larger distances in longer time scales. We predict that the elastic width of the resonance in excited alkali adsorbates on ferromagnetic surfaces can depend on spin orientation in a counterintuitive way. Finally, we quantitatively evaluate the electron–electron and electron–phonon contributions to the electronic excited states widths in ultrathin metal layers. We conclude that confinement and spin effects are key factors in the behavior of electron dynamics at metal surfaces.We acknowledge partial support by the Basque government, the University of the Basque Country UPV/EHU (Grant No. 9/UPV 00206.215-13639/2001), and the Spanish Ministerio de Educación y Ciencia (Grant FIS2007-66711-C02-00)