PHOTOCATALYTIC FORMATION OF A CARBAMATE THROUGH ETHANOL-ASSISTED CARBONYLATION OF P-NITROTOLUENE
- A.MALDOTTI
- R.AMADELLI
- L.SAMIOLO
- A. MOLINARI
- A.PENONI
- S.TOLLARI
- S.CENINI
Publication date
January 2005
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1359-7345 Citation count (estimate)
17Abstract
The nitroarene p-nitrotoluene is converted with a selectivity higher than 85% to the corresponding carbamate at room temperature and atmospheric pressure, using photoexcited particles of TiO2 as catalyst and EtOH as carbonylating species
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