Add to ORKGPropargyl bromide was converted to the resp. allenylmagnesium bromide and added to nitro compds. to give N-aryl-N propargylhydroxylamines and N-alkyl-N-propargylhydroxylamines RN(CH2C≡CH)OH I (R = Ph, 4-ClC6H4, 1-naphthyl, hexyl, cyclohexyl, 4-MeC6H4CH2CH2 etc.) in the presence of LiAlH4 and Pd/C. I are not further reduced to give, e.g., N-propargylanilines
We have developed a highly selective method for the synthesis of α,β-unsaturated amides and alkenyl ...
Ethynylation and propargylation of chiral nonracemic polyhydroxylated cyclic nitrones with Grignard ...
The synthesis of a variety of small alpha-branched trifluoroethyl amines was achieved by reaction of...
Propargyl bromide was converted to the resp. allenylmagnesium bromide and added to nitro compds. to ...
In contrast to alkyl Grignard reagents, the allyl reagent reacts with nitroarenes via 1,2-addition t...
Coniugated addition of Grignard reagents to nitro-compounds provide a new method for alkyl-nitroso d...
The reaction of ortho-substituted nitrobenzenes with 3 mol vinylmagnesium halides gives mainly 7-sub...
A New facile and general synthesis of alkylanilines by one-pot reductive alkylation of nitroarenes i...
The reaction of nitrosoarenes and 1-(trimethylsilyl)vinilmagnesium bromide in dibutyl ether represen...
A straightforward synthesis of N-tosylhomosphinganine and N-tosylsedridine has been achieved from tr...
By the reaction of RHgX (X = Cl, Br, OAc) with NOC1, mercury is eliminated as CIHgX and, if R is aro...
Reaction of optically active nitroalkanes with Grignard reagents affords E-Z mixtures of nitrones wh...
Reaction of allyl and benzyl Grignard reagents with functionalized nitroalkanes affords nitrones in ...
Over the past decade modified Ullmann couplings and palladium-catalyzed arylations of nitrogen contg...
We have developed a highly selective method for the synthesis of α,β-unsaturated amides and alkenyl ...
Ethynylation and propargylation of chiral nonracemic polyhydroxylated cyclic nitrones with Grignard ...
The synthesis of a variety of small alpha-branched trifluoroethyl amines was achieved by reaction of...
Propargyl bromide was converted to the resp. allenylmagnesium bromide and added to nitro compds. to ...
In contrast to alkyl Grignard reagents, the allyl reagent reacts with nitroarenes via 1,2-addition t...
Coniugated addition of Grignard reagents to nitro-compounds provide a new method for alkyl-nitroso d...
The reaction of ortho-substituted nitrobenzenes with 3 mol vinylmagnesium halides gives mainly 7-sub...
A New facile and general synthesis of alkylanilines by one-pot reductive alkylation of nitroarenes i...
The reaction of nitrosoarenes and 1-(trimethylsilyl)vinilmagnesium bromide in dibutyl ether represen...
A straightforward synthesis of N-tosylhomosphinganine and N-tosylsedridine has been achieved from tr...
By the reaction of RHgX (X = Cl, Br, OAc) with NOC1, mercury is eliminated as CIHgX and, if R is aro...
Reaction of optically active nitroalkanes with Grignard reagents affords E-Z mixtures of nitrones wh...
Reaction of allyl and benzyl Grignard reagents with functionalized nitroalkanes affords nitrones in ...
Over the past decade modified Ullmann couplings and palladium-catalyzed arylations of nitrogen contg...
We have developed a highly selective method for the synthesis of α,β-unsaturated amides and alkenyl ...
Ethynylation and propargylation of chiral nonracemic polyhydroxylated cyclic nitrones with Grignard ...
The synthesis of a variety of small alpha-branched trifluoroethyl amines was achieved by reaction of...