The sterically hindered tetrakis-(3-(p-tolylpyrazolyl)borate [pz0Tpp-Tol] has been prepared and its reaction with CuX2.nH2O (X = Cl or acetate (OAc), M(NO3)2.6H2O (M = Ni, or Co) and MCl2 (M = Zn or Cd) has been investigated. [M(pz0Tpp-Tol)X(Hpzp-To l)] (M = Cu, X = Cl or OAc; M = Ni or Co, X = NO3) and [M(pz0Tpp-Tol)Cl(Hpzp-T ol)2-n(H2O)n] have been synthesised and their spectroscopic properties described, the five-coordinated Cu species being also structurally characterized. The methyl groups in the para-tolyl fragments of the ligand strongly influences the stoichiometry and structure of the metal complexes
The new ligands dihydrobis[3-(4-pyridyl)pyrazol-1-yl]borate [Bp(4py)](-), hydrotris[3-(4-pyridyl)pyr...
New copper(I) complexes have been synthesized from the reaction between [Cu(CH(3)CN)(4)]PF(, or Cul,...
Two scorpionates sodium trihydro(3-nitro-pyrazol-1-yl) borate (Na[H(3)B(3-(NO(2))pz)]) and sodium hy...
The sterically hindered tetrakis-(3-(p-tolylpyrazolyl)borate [pz0Tpp-Tol] has been prepared and its ...
Mono- and bis-(trialkyl- and triaryl-phosphine)copper(I) derivatives containing anionic bis-, tris- ...
The dihydrobis(3-carboxyethyl-5-methylpyrazolyl)borate ligand, Bp(COOET,Me), reacts with divalent me...
Two l-pyrazolate dicopper derivatives, [Cu2(l-pz)2(Tpx)2] [Tpx = Tp, tris(pyrazol-1-yl)borate or Tp*...
1626-1634Poly nuclear copper(II) complexes [CU2{μ-B(pz)4}(μ-ox)(NO3)(H2O)].2H2O (1. 2H2O), [CU2{μ-B(...
Complexes of formulation [Cu(TpPh)(L)](ClO4) (1-4), where TpPh is anionic tris(3-phenylpyrazolyl)bor...
Volatility studies, electrospray mass spectra and IR in vapour phase were carried out for a series o...
Complexes of formulation [Cu(Tp(Ph))(L)](ClO4) (1-4), where Tp(Ph) is anionic tris(3-phenylpyrazolyl...
The new ligands dihydrobis[3-(4-pyridyl)pyrazol-1-yl]borate [Bp(4py)](-), hydrotris[3-(4-pyridyl)pyr...
New copper(I) complexes have been synthesized from the reaction between [Cu(CH(3)CN)(4)]PF(, or Cul,...
Two scorpionates sodium trihydro(3-nitro-pyrazol-1-yl) borate (Na[H(3)B(3-(NO(2))pz)]) and sodium hy...
The sterically hindered tetrakis-(3-(p-tolylpyrazolyl)borate [pz0Tpp-Tol] has been prepared and its ...
Mono- and bis-(trialkyl- and triaryl-phosphine)copper(I) derivatives containing anionic bis-, tris- ...
The dihydrobis(3-carboxyethyl-5-methylpyrazolyl)borate ligand, Bp(COOET,Me), reacts with divalent me...
Two l-pyrazolate dicopper derivatives, [Cu2(l-pz)2(Tpx)2] [Tpx = Tp, tris(pyrazol-1-yl)borate or Tp*...
1626-1634Poly nuclear copper(II) complexes [CU2{μ-B(pz)4}(μ-ox)(NO3)(H2O)].2H2O (1. 2H2O), [CU2{μ-B(...
Complexes of formulation [Cu(TpPh)(L)](ClO4) (1-4), where TpPh is anionic tris(3-phenylpyrazolyl)bor...
Volatility studies, electrospray mass spectra and IR in vapour phase were carried out for a series o...
Complexes of formulation [Cu(Tp(Ph))(L)](ClO4) (1-4), where Tp(Ph) is anionic tris(3-phenylpyrazolyl...
The new ligands dihydrobis[3-(4-pyridyl)pyrazol-1-yl]borate [Bp(4py)](-), hydrotris[3-(4-pyridyl)pyr...
New copper(I) complexes have been synthesized from the reaction between [Cu(CH(3)CN)(4)]PF(, or Cul,...
Two scorpionates sodium trihydro(3-nitro-pyrazol-1-yl) borate (Na[H(3)B(3-(NO(2))pz)]) and sodium hy...