A powerful new oxidation agent towards metallic gold powder: N,N’-dimethylperhydrodiazepine-2,3-dithione (D) bis(diiodine). Synthesis and X-ray structure of [AuDI2]I3

Characterization and Structural Insights of the Reaction Products by Direct Leaching of the Noble Metals Au, Pd and Cu with N,N′-Dimethyl-piperazine-2,3-dithione/I2 Mixtures

Angela Serpe
Luca Pilia
Davide Balestri
Luciano Marchiò
Paola Deplano

August 2021

In the context of new efficient and safe leaching agents for noble metals, this paper describes the ...

From trash to resource: a green approach to noble-metals dissolution and recovery

Serpe A
Mercuri ML
Artizzu F
Espa D
Rigoldi A
Deplano P

January 2014

A process based on the lixiviant properties of organic mixtures of dihalogen/S,S-ligands, N,N′-dimet...

CLUSTER COMPLEXES

Hanan E. Abdou
B. Sc
E. Abdou
Dr. Mitchell
R. M. Bruce

January 2001

Chemical oxidation of dinuclear gold(I) thiolates of the formula LLAu2(SC6H4CH3)2 2[LL = dppp, bis(d...

A powerful new oxidation agent towards metallic gold powder: N,N’-dimethylperhydrodiazepine-2,3-dithione (D) bis(diiodine). Synthesis and X-ray structure of [AuDI2]I3

Bigoli F
Pellinghelli MA
Pintus G
Trogu EF
DEPLANO, PAOLA
MERCURI, MARIA LAURA
SERPE, ANGELA

January 1998

The oxidation of gold powder by a new safe and powerful oxidising reagent, the bis-diiodine adduct o...

Gold oxidative dissolution by (thioamide)-I2 adducts

ISAIA, FRANCESCO
ARAGONI, MARIA CARLA
ARCA, MASSIMILIANO
CALTAGIRONE, CLAUDIA
Demartin F
Garau A
LIPPOLIS, VITO

January 2013

Elemental gold powder is easily oxidised under mild reaction conditions with 1 : 1 I2-adducts of the...

Oxidant/complexing properties of the methimazole (MeImHS)/iodine system towards palladium and gold metals. Crystal structure of the complex cation [PdII(MeImHS)4]2+ balanced by a tetraiodide/iodide mixture

F. Isaia
M.C. Aragoni
M. Arca
C. Caltagirone
C. Castellano
F. Demartin
A. Garau
V. Lippolis
T. Pivetta

February 2020

This paper reports on the oxidative dissolution ability in dichloromethane and water of the methimaz...

Oxidant/Complexing Properties of the Methimazole (MeImHS)/Iodine System Towards Palladium and Gold Metals. Crystal structure of the complex cation [PdII(MeImHS)4]2+ balanced by a tetraiodide/iodide mixture

Francesco Isaia
Maria Carla Aragoni
Massimiliano Arca
Claudia Caltagirone
Carlo Castellano
Francesco Demartin
Alessandra Garau
Vito Lippolis
Tiziana Pivetta

January 2020

This paper reports on the oxidative dissolution ability in dichloromethane and water of the methimaz...

Gold(0) and gold(III) reactivity towards the tetraphenyldithioimidodiphosphinic acid, [Ph2P(S)NHP(S)Ph2]

ARAGONI M
M. CARLA ARAGONI
M. ARCA
M. BONARIA CARREA
FRANCESCO A. DEVILLANOVA
ALESSANDRA GARAU
FRANCESCO ISAIA
VITO LIPPOLIS
MARCO MARCELLI
CRISTIAN SILVESTRU
AND GAETANO VERANI

January 2005

The reaction of gold powder with the iodine adduct of Ph2P(S)NHP(S)Ph2 (HL) in Et2O gave the complex...

Gold and palladium oxidation/complexation in water by a thioamide–iodine leaching system

ISAIA, FRANCESCO
ARAGONI, MARIA CARLA
ARCA, MASSIMILIANO
CALTAGIRONE, CLAUDIA
Castellano, Carlo
DE FILIPPO, GRETA
GARAU, ALESSANDRA
LIPPOLIS, VITO
PIVETTA, TIZIANA

January 2017

This paper concerns the oxidative dissolution ability of a thioamide/iodine leaching system in water...

Gold and palladium oxidation/complexation in water by a thioamide-iodine leaching system

F. Isaia
M.C. Aragoni
M. Arca
C. Caltagirone
C. Castellano
G. De Filippo
A. Garau
V. Lippolis
T. Pivetta

January 2017

This paper concerns the oxidative dissolution ability of a thioamide/iodine leaching system in water...

On the Use of the Bis(diiodine) Adduct of 1,4-Dimethylperhydro-1,4-diazepine-2,3-dithione (Me2dazdt) to Recover Liquid Mercury Producing [Hg(Me2dazdt)I2] in a One-Step Reaction

F. BIGOLI
M. C. CABRAS
L. MARCHIO'
E. F. TROGU
DEPLANO, PAOLA
MERCURI, MARIA LAURA
SERPE, ANGELA

January 2004

Diiodine adducts with cyclic dithio-oxamides, where complexing and oxidising properties coexist in t...

Facile oxidative addition of aryl iodides to Gold(I) by ligand design: Bending turns on reactivity

Joost, M.
Zeineddine, A.
Estévez, L.
Mallet-Ladeira, S.
Miqueu, K.
Amgoune, A.
Bourissou, D.

January 2014

International audienceThanks to rational ligand design, the first gold(I) complexes to undergo oxida...

Gold oxidative dissolution by (thioamide)–I2 adducts

F. Isaia
M.C. Aragoni
M. Arca
C. Caltagirone
F. Demartin
A. Garau
V. Lippolis

January 2013

Elemental gold powder is easily oxidised under mild reaction conditions with 1 : 1 I2-adducts of the...

Charge transfer complexes of dithioxamides with dihalogens as powerful reagents in the dissolution of noble metals

SERPE, ANGELA
ARTIZZU, FLAVIA
MERCURI, MARIA LAURA
PILIA, LUCA
DEPLANO, PAOLA

January 2008

Commonly involved in the recovery/refining processes of noble metals (NMs), coordination chemistry i...

Design and Synthetic Applications of High Oxidation State Iodine and Gold Complexes

Lachlan Sharp-Bucknall (9479738)

July 2023

A thesis submitted in total fulfilment of the requirements for the degree of Doctor of Philosophy to...

Characterization and Structural Insights of the Reaction Products by Direct Leaching of the Noble Metals Au, Pd and Cu with N,N′-Dimethyl-piperazine-2,3-dithione/I2 Mixtures

Angela Serpe
Luca Pilia
Davide Balestri
Luciano Marchiò
Paola Deplano

August 2021

In the context of new efficient and safe leaching agents for noble metals, this paper describes the ...

From trash to resource: a green approach to noble-metals dissolution and recovery

Serpe A
Mercuri ML
Artizzu F
Espa D
Rigoldi A
Deplano P

January 2014

A process based on the lixiviant properties of organic mixtures of dihalogen/S,S-ligands, N,N′-dimet...

CLUSTER COMPLEXES

Hanan E. Abdou
B. Sc
E. Abdou
Dr. Mitchell
R. M. Bruce

January 2001

Chemical oxidation of dinuclear gold(I) thiolates of the formula LLAu2(SC6H4CH3)2 2[LL = dppp, bis(d...

A powerful new oxidation agent towards metallic gold powder: N,N’-dimethylperhydrodiazepine-2,3-dithione (D) bis(diiodine). Synthesis and X-ray structure of [AuDI2]I3

Bigoli F
Pellinghelli MA
Pintus G
Trogu EF
DEPLANO, PAOLA
MERCURI, MARIA LAURA
SERPE, ANGELA

January 1998

The oxidation of gold powder by a new safe and powerful oxidising reagent, the bis-diiodine adduct o...

Gold oxidative dissolution by (thioamide)-I2 adducts

ISAIA, FRANCESCO
ARAGONI, MARIA CARLA
ARCA, MASSIMILIANO
CALTAGIRONE, CLAUDIA
Demartin F
Garau A
LIPPOLIS, VITO

January 2013

Elemental gold powder is easily oxidised under mild reaction conditions with 1 : 1 I2-adducts of the...

Oxidant/complexing properties of the methimazole (MeImHS)/iodine system towards palladium and gold metals. Crystal structure of the complex cation [PdII(MeImHS)4]2+ balanced by a tetraiodide/iodide mixture

F. Isaia
M.C. Aragoni
M. Arca
C. Caltagirone
C. Castellano
F. Demartin
A. Garau
V. Lippolis
T. Pivetta

February 2020

This paper reports on the oxidative dissolution ability in dichloromethane and water of the methimaz...

Oxidant/Complexing Properties of the Methimazole (MeImHS)/Iodine System Towards Palladium and Gold Metals. Crystal structure of the complex cation [PdII(MeImHS)4]2+ balanced by a tetraiodide/iodide mixture

Francesco Isaia
Maria Carla Aragoni
Massimiliano Arca
Claudia Caltagirone
Carlo Castellano
Francesco Demartin
Alessandra Garau
Vito Lippolis
Tiziana Pivetta

January 2020

This paper reports on the oxidative dissolution ability in dichloromethane and water of the methimaz...

Gold(0) and gold(III) reactivity towards the tetraphenyldithioimidodiphosphinic acid, [Ph2P(S)NHP(S)Ph2]

ARAGONI M
M. CARLA ARAGONI
M. ARCA
M. BONARIA CARREA
FRANCESCO A. DEVILLANOVA
ALESSANDRA GARAU
FRANCESCO ISAIA
VITO LIPPOLIS
MARCO MARCELLI
CRISTIAN SILVESTRU
AND GAETANO VERANI

January 2005

The reaction of gold powder with the iodine adduct of Ph2P(S)NHP(S)Ph2 (HL) in Et2O gave the complex...

Gold and palladium oxidation/complexation in water by a thioamide–iodine leaching system

ISAIA, FRANCESCO
ARAGONI, MARIA CARLA
ARCA, MASSIMILIANO
CALTAGIRONE, CLAUDIA
Castellano, Carlo
DE FILIPPO, GRETA
GARAU, ALESSANDRA
LIPPOLIS, VITO
PIVETTA, TIZIANA

January 2017

This paper concerns the oxidative dissolution ability of a thioamide/iodine leaching system in water...

Gold and palladium oxidation/complexation in water by a thioamide-iodine leaching system

F. Isaia
M.C. Aragoni
M. Arca
C. Caltagirone
C. Castellano
G. De Filippo
A. Garau
V. Lippolis
T. Pivetta

January 2017

This paper concerns the oxidative dissolution ability of a thioamide/iodine leaching system in water...

On the Use of the Bis(diiodine) Adduct of 1,4-Dimethylperhydro-1,4-diazepine-2,3-dithione (Me2dazdt) to Recover Liquid Mercury Producing [Hg(Me2dazdt)I2] in a One-Step Reaction

F. BIGOLI
M. C. CABRAS
L. MARCHIO'
E. F. TROGU
DEPLANO, PAOLA
MERCURI, MARIA LAURA
SERPE, ANGELA

January 2004

Diiodine adducts with cyclic dithio-oxamides, where complexing and oxidising properties coexist in t...

Facile oxidative addition of aryl iodides to Gold(I) by ligand design: Bending turns on reactivity

Joost, M.
Zeineddine, A.
Estévez, L.
Mallet-Ladeira, S.
Miqueu, K.
Amgoune, A.
Bourissou, D.

January 2014

International audienceThanks to rational ligand design, the first gold(I) complexes to undergo oxida...

Gold oxidative dissolution by (thioamide)–I2 adducts

F. Isaia
M.C. Aragoni
M. Arca
C. Caltagirone
F. Demartin
A. Garau
V. Lippolis

January 2013

Elemental gold powder is easily oxidised under mild reaction conditions with 1 : 1 I2-adducts of the...

Charge transfer complexes of dithioxamides with dihalogens as powerful reagents in the dissolution of noble metals

SERPE, ANGELA
ARTIZZU, FLAVIA
MERCURI, MARIA LAURA
PILIA, LUCA
DEPLANO, PAOLA

January 2008

Commonly involved in the recovery/refining processes of noble metals (NMs), coordination chemistry i...

Design and Synthetic Applications of High Oxidation State Iodine and Gold Complexes

Lachlan Sharp-Bucknall (9479738)

July 2023

A thesis submitted in total fulfilment of the requirements for the degree of Doctor of Philosophy to...

Characterization and Structural Insights of the Reaction Products by Direct Leaching of the Noble Metals Au, Pd and Cu with N,N′-Dimethyl-piperazine-2,3-dithione/I2 Mixtures

Angela Serpe
Luca Pilia
Davide Balestri
Luciano Marchiò
Paola Deplano

August 2021

In the context of new efficient and safe leaching agents for noble metals, this paper describes the ...

From trash to resource: a green approach to noble-metals dissolution and recovery

Serpe A
Mercuri ML
Artizzu F
Espa D
Rigoldi A
Deplano P

January 2014

A process based on the lixiviant properties of organic mixtures of dihalogen/S,S-ligands, N,N′-dimet...

CLUSTER COMPLEXES

Hanan E. Abdou
B. Sc
E. Abdou
Dr. Mitchell
R. M. Bruce

January 2001

Chemical oxidation of dinuclear gold(I) thiolates of the formula LLAu2(SC6H4CH3)2 2[LL = dppp, bis(d...

A powerful new oxidation agent towards metallic gold powder: N,N’-dimethylperhydrodiazepine-2,3-dithione (D) bis(diiodine). Synthesis and X-ray structure of [AuDI2]I3

Abstract

Extracted data

A powerful new oxidation agent towards metallic gold powder: N,N’-dimethylperhydrodiazepine-2,3-dithione (D) bis(diiodine). Synthesis and X-ray structure of [AuDI2]I3

Abstract

Extracted data

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