Variability of ozone and oxides of nitrogen in the tropical city, Bengaluru, India

Bengaluru, also considered India's Silicon Valley, has seen steady growth in population over the years. Bengaluru's rapid development has resulted in dwindling reservoirs, increased traffic congestion, high levels of air pollution, and, to some measure, a rise in summer temperatures. As a result of these changes in urban form over the last decade, anthropogenic heat fluxes for ozone production have increased. However, an observational study on the effects of growing urbanisation on trace gases in Bengaluru for various seasons and periods of the day is missing. Hence, in situ measurements of O3, NO, NO2, and NOX concentrations were carried out at Bengaluru, India, from January 2015 to December 2018. The data were examined for diurnal and interannual variations in trace gas mixing concentrations. The diurnal trend in O3 exhibits unimodal behaviour. Changes in photochemistry, local meteorology, and the planetary boundary layer's distinctive features cause a rise in the value of concentrations and lead to a peak. In contrast, the diurnal trend in NO, NO2, and NOX displayed a bimodal peak due to the combined effect of vehicular emissions and the planetary boundary layer. The link involving the oxidant OX (O3 + NO2) and NOx levels were investigated to determine the NOx-independent regional and NOx-dependent local contributions to OX in the atmosphere. Daytime contributions are higher than night-time contributions, according to the present study. The observed anomalies could be the consequence of photochemical processes that produce OX