Energy storage is a vital aspect for the successful implementation of renewable energy resources on a global scale. Herein, we investigated the redox cycle of nickel(II) bis(diethyldithiocarbamate), NiII(dtc)2, for potential use as a multielectron storage catholyte in nonaqueous redox flow batteries (RFBs). Previous studies have shown that the unique redox cycle of NiII(dtc)2 offers 2e– chemistry upon oxidation from NiII → NiIV but 1e– chemistry upon reduction from NiIV → NiIII → NiII. Electrochemical experiments presented here show that the addition of as little as 10 mol % ZnII(ClO4)2 to the electrolyte consolidates the two 1e– reduction peaks into a single 2e– reduction where [NiIV(dtc)3]+ is reduced directly to NiII(dtc)2. This catalyti...
This thesis work focuses on the zinc-iodine redox flow battery system with ananalysis of the electro...
Non-aqueous redox flow batteries (NAqRFBs) have recently received considerable attention as promisin...
Metal-supported fuel cells (MSCs) are promising candidates for not only stationary but also mobile a...
The unique redox cycle of NiII(dtc)2, where dtc– is N,N-diethyldithiocarbamate, in acetonitrile disp...
The development of nonaqueous redox flow batteries (NRFBs) has been impeded by a lack of electroacti...
This is the author accepted manuscript. The final version is available from Elsevier via the DOI in ...
The use of electricity generated from clean and renewable sources, such as water, wind, or sunlight,...
Color poster with text, images, formulas, and graphs.In today’s economy, energy based on fossil fuel...
In this project, we investigated the electrochemical behavior of [Ni(PPh2NPh2)2]2+, a premiere catal...
The ongoing search for new electroactive materials for next-generation redox flow batteries has with...
Abstract The development of efficient earth-abundant electrocatalysts for oxygen reduction, oxygen e...
Metal-supported fuel cells (MSCs) are promising candidates for non-stationary applications like auxi...
The redox behavior of nickel(II) and nickel(IV) species derived from a few hexadentate ligands of ty...
The Zn–Ce flow battery is a recently introduced hybrid redox flow battery (RFB) but has been extensi...
Each battery technology possesses intrinsic advantages and disadvantages, e.g., nickel–metal hydride...
This thesis work focuses on the zinc-iodine redox flow battery system with ananalysis of the electro...
Non-aqueous redox flow batteries (NAqRFBs) have recently received considerable attention as promisin...
Metal-supported fuel cells (MSCs) are promising candidates for not only stationary but also mobile a...
The unique redox cycle of NiII(dtc)2, where dtc– is N,N-diethyldithiocarbamate, in acetonitrile disp...
The development of nonaqueous redox flow batteries (NRFBs) has been impeded by a lack of electroacti...
This is the author accepted manuscript. The final version is available from Elsevier via the DOI in ...
The use of electricity generated from clean and renewable sources, such as water, wind, or sunlight,...
Color poster with text, images, formulas, and graphs.In today’s economy, energy based on fossil fuel...
In this project, we investigated the electrochemical behavior of [Ni(PPh2NPh2)2]2+, a premiere catal...
The ongoing search for new electroactive materials for next-generation redox flow batteries has with...
Abstract The development of efficient earth-abundant electrocatalysts for oxygen reduction, oxygen e...
Metal-supported fuel cells (MSCs) are promising candidates for non-stationary applications like auxi...
The redox behavior of nickel(II) and nickel(IV) species derived from a few hexadentate ligands of ty...
The Zn–Ce flow battery is a recently introduced hybrid redox flow battery (RFB) but has been extensi...
Each battery technology possesses intrinsic advantages and disadvantages, e.g., nickel–metal hydride...
This thesis work focuses on the zinc-iodine redox flow battery system with ananalysis of the electro...
Non-aqueous redox flow batteries (NAqRFBs) have recently received considerable attention as promisin...
Metal-supported fuel cells (MSCs) are promising candidates for not only stationary but also mobile a...