North Atlantic CO2 sink variability revealed by the Go-Ship A25-OVIDE section

EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022.-- This work is distributed under the Creative Commons Attribution 4.0 LicenseAbout 30% of the carbon dioxide derived from human activities (CANTH) has been absorbed by the ocean (DeVries, 2014; Gruber et al., 2019; Friedlingstein et al., 2021), with the North Atlantic (NA) being one of the largest CANTH sinks per unit area (Khatiwala et al., 2013; Sabine et al., 2004). In the NA, oceanic CANTH uptake strongly relies on the meridional overturning circulation and the associated regional winter deep convection. In fact, the formation and deep spreading of Labrador Sea Water stands as a critical CANTH gateway to intermediate and abyssal depths. The NA CANTH uptake has fluctuated over the years according to changes in the North Atlantic Oscillation. Biennial observation of the marine carbonate system along the Go-Ship A25-OVIDE section has allowed us assessing the decadal and interannual variability of the CANTH storage in the subpolarNA from 2002 to 2021. In this study, we investigate 1) the trend of CANTH and 2) the relationship between the CANTH saturation, the apparent oxygen utilization, and the ventilation of the water masses between the A25-OVIDE section and the Greenland-Iceland-Scotland sills during 2002-2021. We divided the A25-OVIDE section into three main basins (Irminger, Iceland, and Eastern NA). Our results show that the Irminger Basin presents a more homogenous CANTH profile and higher CANTH saturation values at depth than the other two basins, which is related to the pronounced convective activity in the Irminger Basin. In contrast, the Eastern NA Basin has higher CANTH values at the surface due to its higher surface temperature, but its deep water masses show the lowest CANTH values since they are the less ventilated in the section. Our analysis also reveals that, overall, the NA CANTH storage has increased during 2002-2021, but varied according to the ventilation changes. While the Eastern NA water masses experienced a relatively constant, although shallower, average ventilation, the Irminger and Iceland Basins underwent a less steady CANTH uptake pattern characterized by alternating periods of strong and weak CANTH storageN