The influence of plasma chemical treatment of the surface of massive nickel on the kinetic characteristics of isopropanol dehydrogenation was studied. A high-frequency electrodeless hydrogen plasma was shown to increase the activity of the catalyst over the temperature range 525-673 K. A sharper increase in activity occurred at 525-634 K after treatment of the surface of nickel with a glow-discharge oxygen plasma. Changes in the rate constants and experimental activation energies were interpreted considering the difference of the work functions of electrons in the ferromagnetic state of the metal below the Curie point (634 K) and in the paramagnetic state (634-673 K). Copyright © 2005 by Pleiades Publishing, Inc
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The effect of the treatment of the 5 wt % Cu/SiO 2 (I) and (5 wt % Cu + 0.5 wt % Ce)/SiO 2 (II) cata...
The influence of plasma chemical treatment of the surface of massive nickel on the kinetic character...
The dehydrogenation of isopropanol was studied at 440-680 K to find that the activity of the Ni(1 wt...
The kinetics of the desorption of firmly adsorbed hydrogen from the surface of massive foamed nickel...
The dependence of the activity of the (Ni 20 wt %-Mn 4 wt %)/SiO 2 catalyst on the treatment of its ...
The adsorption isotherms of isopropanol on a Ni catalyst (15 wt % on SiO2) in the temperature range ...
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The influence of plasmochemical treatments of the 5 wt % Cu/SiO 2 catalyst and cerium additives on t...
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