Permeable reactive barriers for acid mine drainage treatment : a review

Contaminated water flowing from abandoned mines is one of the most significant contributors to water pollution. Acid mine drainage (AMD) can have severe impacts on aquatic resources, can stunt terrestrial plant growth and harm wetlands, contaminate groundwater, raise water treatment costs, and damage concrete and metal structures. Permeable reactive barriers (PRBs) are one of the passive treatment technologies widely accepted for sustainable in situ remediation of contaminated groundwater and may be used in the management of localised seepage plumes from mine residues that contaminate shallow groundwater. These barriers provide chemical interactions with AMD as the polluted water flows through it. The ability of PRBs to remediate contaminants is dependent on the type of reactive material used. Some of the reactive media remove contaminants through physical contact while others work by altering the biogeochemical processes in the treatment zone, thus providing conditions conducive for contaminant immobilization or (bio) degradation. A variety of materials has been employed to remove contaminants including heavy metals, chlorinated solvents, aromatic hydrocarbons, and pesticides. This paper gives an overview of the PRB technology, which includes the advantages and limitations of the PRB, the types of reactive materials used, laboratory treatability tests used to evaluate suitable reactive materials and to aid in the designing and the implementation of the PRB and the installations schemes used in PRB field application