The dioxygen molecule has two bound states, singlet and triplet, which are different in energy, lifetime, and reactivity. In the context of oxygen electrocatalysis as applied to fuel cells and water splitting the involved O2 is typically considered to be exclusively in its triplet ground state. However, applying spin-conservation rules for the transformation between triplet O2 and singlet OH−/H2O reaction intermediates predicts an additional free energy barrier associated with the required spin flip. As a result, for conditions under which both can form, the formation of triplet dioxygen from the singlet OH−/H2O might be slower than the formation of singlet O2. Correspondingly, singlet O2 might be more active than triplet O2 in the oxygen r...
The authors discuss the advances made in both mechanistic and synthetic aspects of singlet oxygen ch...
Carbon materials based catalysts (CMCs) are extensively investigated to replace expensive noble meta...
l. Introduction 1.1. Singlet oxygen Singlet molecular oxygen 'o, 1'Á,) has been intensively investig...
The reduction of molecular oxygen in triplet and singlet spin states at metal electrodes is analyzed...
Electrochemical reduction of oxygen is considered as a new strategy to achieve decentralized prepara...
Oxygen evolution and reduction reactions play a critical role in determining the efficiency of the w...
As we are witnessing the renaissance of electrochemistry, particularly noticeable is emerging intere...
Oxygen involved reactions, including oxygen reduction (ORR) and oxygen evolution reactions (OERs), p...
Cofactor-less oxygenases perform challenging catalytic reactions between singlet co-substrates and t...
Department of Chemistry, College of Science, Sukhadia University, Udaipur-313 001, India Department...
The electrochemical oxygen reduction reaction (ORR) mechanism was generally considered to be O₂→ OOH...
The electroreduction of O_2 to H_2O in aqueous acid at potentials close to the thermodynamically pe...
Cofactor-less oxygenases perform challenging catalytic reactions between singlet co-substrates and t...
Electrocatalytic production of hydrogen peroxide (H2O2) via the 2e− transfer route of the oxygen red...
Electrochemical reduction of oxygen is considered as a new strategy to achieve decentralized prepara...
The authors discuss the advances made in both mechanistic and synthetic aspects of singlet oxygen ch...
Carbon materials based catalysts (CMCs) are extensively investigated to replace expensive noble meta...
l. Introduction 1.1. Singlet oxygen Singlet molecular oxygen 'o, 1'Á,) has been intensively investig...
The reduction of molecular oxygen in triplet and singlet spin states at metal electrodes is analyzed...
Electrochemical reduction of oxygen is considered as a new strategy to achieve decentralized prepara...
Oxygen evolution and reduction reactions play a critical role in determining the efficiency of the w...
As we are witnessing the renaissance of electrochemistry, particularly noticeable is emerging intere...
Oxygen involved reactions, including oxygen reduction (ORR) and oxygen evolution reactions (OERs), p...
Cofactor-less oxygenases perform challenging catalytic reactions between singlet co-substrates and t...
Department of Chemistry, College of Science, Sukhadia University, Udaipur-313 001, India Department...
The electrochemical oxygen reduction reaction (ORR) mechanism was generally considered to be O₂→ OOH...
The electroreduction of O_2 to H_2O in aqueous acid at potentials close to the thermodynamically pe...
Cofactor-less oxygenases perform challenging catalytic reactions between singlet co-substrates and t...
Electrocatalytic production of hydrogen peroxide (H2O2) via the 2e− transfer route of the oxygen red...
Electrochemical reduction of oxygen is considered as a new strategy to achieve decentralized prepara...
The authors discuss the advances made in both mechanistic and synthetic aspects of singlet oxygen ch...
Carbon materials based catalysts (CMCs) are extensively investigated to replace expensive noble meta...
l. Introduction 1.1. Singlet oxygen Singlet molecular oxygen 'o, 1'Á,) has been intensively investig...