In this study, we consider general Markov chains (MC) defined by a transition probability (kernel) that is finitely additive. These Markov chains were constructed by S. Ramakrishnan within the concepts and symbolism of game theory. Here, we study these MCs by using the operator approach. In our work, the state space (phase space) of the MC has any cardinality and the sigma-algebra is discrete. The construction of a phase space allows us to decompose the Markov kernel (and the Markov operators that it generates) into the sum of two components: countably additive and purely finitely additive kernels. We show that the countably additive kernel is atomic. Some properties of Markov operators with a purely finitely additive kernel and their invar...