Reactivity of Phosphacarbamates: Transfer of the Carbamate Group Promoted by Metal Assisted Electrophilic Attack at the Carbon Dioxide Moiety

Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters

M. CARAFA
QUARANTA E

January 2009

Aminolysis of organic carbonates is a suitable phosgene-free synthetic route to carbamate esters. Th...

Mechanistic Studies on the Role of Carbon Dioxide in the Synthesis of Methylcarbamates from Amines and Dialkylcarbonates in the Presence of CO2

Aresta M
QUARANTA, Eugenio

January 1991

N-alkylmethylcarbamates have been synthesized from amines and dimethylcarbonate (DMC) in the presenc...

Cyanomethyl Anion/Carbon dioxide System: An electrogenerated carboxylating reagent. Synthesis of carbamates under mild and safe conditions

FEROCI M
CASADEI M. A
PALOMBI L
INESI A.
ORSINI, MONICA

January 2003

A new carboxylating reagent (-CH2CN/CO2) was obtained by bubbling CO2 in a CH3CN-TEAP (tetraethy- la...

Reactivity of Phosphacarbamates: Transfer of the Carbamate Group Promoted by Metal Assisted Electrophilic Attack at the Carbon Dioxide Moiety

Aresta M
QUARANTA E

January 1988

Phosphacarbamates have been used in an unprecedented reaction as a source of carbamate group in th...

Alkali-metal-assisted Transfer of Carbamate Group from Phosphocarbamates to Alkyl Halides: a New Easy Way to Alkali-metal Carbamates and to Carbamate Esters

Aresta M
QUARANTA E

January 1992

Phosphocarbamates P(O2CNR2)x(NR2)3 –x(R = alkyl; x= 1 or 2), easily obtainable by insertion of CO2 i...

Biomimetic building-up of the carbamic moiety: the intermediacy of carboxyphosphate analogues in the synthesis of N-aryl carbamate esters from arylamines and organic carbonates promoted by phosphorus acids

M. Aresta
C. Berloco
QUARANTA, Eugenio

January 1995

The reaction of aromatic amines with dimethyl carbonate (DMC) or diphenyl carbonate (DPC) in the pre...

Carbon dioxide catalysis in trans-esterification reaction for the carbamation of amines of industrial interest

DIBENEDETTO A
ARESTA M.
QUARANTA E.

January 2000

Developing clean synthetic methodology for the production of carbamates, avoiding phosgene, is a ver...

The reaction of amines with an electrogenerated base. Improved synthesis of arylcarbamic esters

FEROCI, Marta
INESI, ACHILLE
Leucio Rossi

January 2000

The electrogenerated base of 2-pyrrolidone reacts with amines and anilines yielding the correspondin...

Carbon Dioxide: an Attractive Building Block for Inorganic and Organic Compounds

BRESCIANI, GIULIO

March 2023

The employment of carbon dioxide as C1-unit to build inorganic and organic compounds was investigate...

Recent advances in the chemistry of metal carbamates

Bresciani G.
Biancalana L.
Pampaloni G.
Marchetti F.

January 2020

Following a related review dating back to 2003, the present review discusses in detail the various s...

REACTION OF ALKALI-METAL TETRAPHENYLBORATES WITH AMINES IN THE PRESENCE OF CO2: A NEW EASY WAY TO ALIPHATIC AND AROMATIC ALKALI-METAL CARBAMATES”

Aresta, M
Dibenedetto, A
Quaranta, E

January 1995

A new method of synthesis of both aliphatic and aromatic alkali-metal carbamates and anhydrous alkyl...

N-Heteroaryl Carbamates from Carbon Dioxide via Chemoselective Superbase Catalysis : Substrate Scope and Mechanistic Investigation

Mannisto, Jere K.
Pavlovic, Ljiljana
Heikkinen, Johannes
Tiainen, Tony
Sahari, Aleksi
Maier, Norbert M.
Rissanen, Kari
Nieger, Martin
Hopmann, Kathrin H.
Repo, Timo

August 2023

We report a mildsuperbase-catalyzed and nitrogen-selective carboxylationof N-heteroaryls, with subse...

Efficient carbamate synthesis

Jung, Kyung Woon

June 2002

A method of preparing carbamates of the general formula RR’—N—CO2—R” by reacting an amine with carbo...

Hydrolysis of a carbamate triggered by coordination of metal ions

Fernández Fariña, Sandra
Martínez Calvo, Miguel
Romero, María J.
Seco, José M.
Zaragoza, Guillermo
Pedrido, Rosa
González-Noya, Ana M.

July 2022

The mechanism of carbamate activation promoted by different metal ions has been explored in this wor...

Conversion of primary amines to carbamate esters using palladium chloride and di-tert-butyl peroxide. Double carbonylation of secondary amines

Alper Howard
Vasapollo Giuseppe
Hartstock Frederick W
Mlekuz Michael
Smit David J H
Morris George E.

January 1987

Primary aliph. and arom. amines react with carbon monoxide and di-tert-Bu peroxide in alc., catalyze...

Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters

M. CARAFA
QUARANTA E

January 2009

Aminolysis of organic carbonates is a suitable phosgene-free synthetic route to carbamate esters. Th...

Mechanistic Studies on the Role of Carbon Dioxide in the Synthesis of Methylcarbamates from Amines and Dialkylcarbonates in the Presence of CO2

Aresta M
QUARANTA, Eugenio

January 1991

N-alkylmethylcarbamates have been synthesized from amines and dimethylcarbonate (DMC) in the presenc...

Cyanomethyl Anion/Carbon dioxide System: An electrogenerated carboxylating reagent. Synthesis of carbamates under mild and safe conditions

FEROCI M
CASADEI M. A
PALOMBI L
INESI A.
ORSINI, MONICA

January 2003

A new carboxylating reagent (-CH2CN/CO2) was obtained by bubbling CO2 in a CH3CN-TEAP (tetraethy- la...

Reactivity of Phosphacarbamates: Transfer of the Carbamate Group Promoted by Metal Assisted Electrophilic Attack at the Carbon Dioxide Moiety

Aresta M
QUARANTA E

January 1988

Phosphacarbamates have been used in an unprecedented reaction as a source of carbamate group in th...

Alkali-metal-assisted Transfer of Carbamate Group from Phosphocarbamates to Alkyl Halides: a New Easy Way to Alkali-metal Carbamates and to Carbamate Esters

Aresta M
QUARANTA E

January 1992

Phosphocarbamates P(O2CNR2)x(NR2)3 –x(R = alkyl; x= 1 or 2), easily obtainable by insertion of CO2 i...

Biomimetic building-up of the carbamic moiety: the intermediacy of carboxyphosphate analogues in the synthesis of N-aryl carbamate esters from arylamines and organic carbonates promoted by phosphorus acids

M. Aresta
C. Berloco
QUARANTA, Eugenio

January 1995

The reaction of aromatic amines with dimethyl carbonate (DMC) or diphenyl carbonate (DPC) in the pre...

Carbon dioxide catalysis in trans-esterification reaction for the carbamation of amines of industrial interest

DIBENEDETTO A
ARESTA M.
QUARANTA E.

January 2000

Developing clean synthetic methodology for the production of carbamates, avoiding phosgene, is a ver...

The reaction of amines with an electrogenerated base. Improved synthesis of arylcarbamic esters

FEROCI, Marta
INESI, ACHILLE
Leucio Rossi

January 2000

The electrogenerated base of 2-pyrrolidone reacts with amines and anilines yielding the correspondin...

Carbon Dioxide: an Attractive Building Block for Inorganic and Organic Compounds

BRESCIANI, GIULIO

March 2023

The employment of carbon dioxide as C1-unit to build inorganic and organic compounds was investigate...

Recent advances in the chemistry of metal carbamates

Bresciani G.
Biancalana L.
Pampaloni G.
Marchetti F.

January 2020

Following a related review dating back to 2003, the present review discusses in detail the various s...

REACTION OF ALKALI-METAL TETRAPHENYLBORATES WITH AMINES IN THE PRESENCE OF CO2: A NEW EASY WAY TO ALIPHATIC AND AROMATIC ALKALI-METAL CARBAMATES”

Aresta, M
Dibenedetto, A
Quaranta, E

January 1995

A new method of synthesis of both aliphatic and aromatic alkali-metal carbamates and anhydrous alkyl...

N-Heteroaryl Carbamates from Carbon Dioxide via Chemoselective Superbase Catalysis : Substrate Scope and Mechanistic Investigation

Mannisto, Jere K.
Pavlovic, Ljiljana
Heikkinen, Johannes
Tiainen, Tony
Sahari, Aleksi
Maier, Norbert M.
Rissanen, Kari
Nieger, Martin
Hopmann, Kathrin H.
Repo, Timo

August 2023

We report a mildsuperbase-catalyzed and nitrogen-selective carboxylationof N-heteroaryls, with subse...

Efficient carbamate synthesis

Jung, Kyung Woon

June 2002

A method of preparing carbamates of the general formula RR’—N—CO2—R” by reacting an amine with carbo...

Hydrolysis of a carbamate triggered by coordination of metal ions

Fernández Fariña, Sandra
Martínez Calvo, Miguel
Romero, María J.
Seco, José M.
Zaragoza, Guillermo
Pedrido, Rosa
González-Noya, Ana M.

July 2022

The mechanism of carbamate activation promoted by different metal ions has been explored in this wor...

Conversion of primary amines to carbamate esters using palladium chloride and di-tert-butyl peroxide. Double carbonylation of secondary amines

Alper Howard
Vasapollo Giuseppe
Hartstock Frederick W
Mlekuz Michael
Smit David J H
Morris George E.

January 1987

Primary aliph. and arom. amines react with carbon monoxide and di-tert-Bu peroxide in alc., catalyze...

Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters

M. CARAFA
QUARANTA E

January 2009

Aminolysis of organic carbonates is a suitable phosgene-free synthetic route to carbamate esters. Th...

Mechanistic Studies on the Role of Carbon Dioxide in the Synthesis of Methylcarbamates from Amines and Dialkylcarbonates in the Presence of CO2

Aresta M
QUARANTA, Eugenio

January 1991

N-alkylmethylcarbamates have been synthesized from amines and dimethylcarbonate (DMC) in the presenc...

Cyanomethyl Anion/Carbon dioxide System: An electrogenerated carboxylating reagent. Synthesis of carbamates under mild and safe conditions

FEROCI M
CASADEI M. A
PALOMBI L
INESI A.
ORSINI, MONICA

January 2003

A new carboxylating reagent (-CH2CN/CO2) was obtained by bubbling CO2 in a CH3CN-TEAP (tetraethy- la...

Reactivity of Phosphacarbamates: Transfer of the Carbamate Group Promoted by Metal Assisted Electrophilic Attack at the Carbon Dioxide Moiety

Abstract

Extracted data

Reactivity of Phosphacarbamates: Transfer of the Carbamate Group Promoted by Metal Assisted Electrophilic Attack at the Carbon Dioxide Moiety

Abstract

Extracted data

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