Effects of the reaction temperature and Ba/Ti precursor ratio on the crystallite size of BaTiO₃ in hydrothermal synthesis

Nanocrystalline BaTiO3 has been prepared by hydrothermal synthesis from titanium isopropoxide and barium hydroxide octahydrate. Reaction conditions including synthesis temperature and Ba/Ti precursor ratio have been explored with the aim of producing BaTiO3 with small crystallites and low concentration of defects. It has been found that the crystallite/particle size and tetragonality of the BaTiO3 samples increase as the synthesis temperature increases; and the crystallite/particle size of BaTiO3 is also affected by the Ba/Ti precursor ratio. The BaTiO3 sample synthesised using a Ba/Ti precursor ratio of 2:1 at a reaction temperature of 120 °C exhibited homogeneous crystallites of the smallest size of 107 nm. Additionally, the Ba/Ti precursor ratio of 2:1 with synthesis temperature of 220 °C was found to produce smaller concentration of defects in BaTiO3