Interface effects in the electronic structure of TiO2 deposited on MgO, Al2O3 and SiO2 substrates

We report the Ti 2p X ray absorption XAS and resonant photoemission RPES spectra of one equivalent TiO2 monolayer grown on MgO, Al2O3 and SiO2 substrates. The Ti 2p XAS spectra of these systems were compared to atomic multipiet calculations projected in different octahedral crystal fields. The comparison indicates that the crystal field splitting and the Ti O hybridization decrease along the MgO, Al2O3 and SiO2 series. The analysis of the RPES spectra provides the Ti 3d contributions to the valence band in these systems. These were compared to configuration interaction calculations of a TiO6 cluster for different Ti 3d O 2p hybridizations. The Ti 3d states in the valence band shift to lower binding energies along the MgO, Al2O3 and SiO2 series. These effects are attributed to changes in the electronic structure at the interface, which, in turn, are related to the formation of cross linking Ti O M M Mg, Al, and Si bond