High-Temperature Tempered Martensite Embrittlement in Quenched-and-Tempered Offshore Steels

Embrittlement induced by high-temperature tempering was investigated in two quenched-and-tempered offshore steels. Electron backscattering diffraction and analysis of Kernel average misorientation were applied to study the coalescence of martensite; transmission Kikuchi diffraction coupled with compositional mapping was used to characterize the martensite/austenite (M/A) phases. It is suggested that the formation of lenticular martensite along prior austenite grain boundaries or packet boundaries primarily explains the embrittlement in conventional S690Q steel, which has a higher carbon content. This embrittlement can be cured by additional heat treatment to decompose martensite into ferrite and cementite. In a newly designed NiCu steel with reduced carbon content, new lath martensite formed along interlath or inter-block boundaries of prior martensite. This microstructure is less detrimental to the impact toughness of the steel