Mineralogical and Geochemical Compositions of the No. 5 Coal in Chuancaogedan Mine, Junger Coalfield, China

This paper reports the mineralogy and geochemistry of the Early Permian No. 5 coal from the Chuancaogedan Mine, Junger Coalfield, China, using optical microscopy, scanning electron microscopy (SEM), Low-temperature ashing X-ray diffraction (LTA-XRD) in combination with Siroquant software, X-ray fluorescence (XRF), and inductively coupled plasma mass spectrometry (ICP-MS). The minerals in the No. 5 coal from the Chuancaogedan Mine dominantly consist of kaolinite, with minor amounts of quartz, pyrite, magnetite, gypsum, calcite, jarosite and mixed-layer illite/smectite (I/S). The most abundant species within high-temperature plasma-derived coals were SiO2 (averaging 16.90%), Al2O3 (13.87%), TiO2 (0.55%) and P2O5 (0.05%). Notable minor and trace elements of the coal include Zr (245.89 mg/kg), Li (78.54 mg/kg), Hg (65.42 mg/kg), Pb (38.95 mg/kg), U (7.85 mg/kg) and Se (6.69 mg/kg). The coal has an ultra-low sulfur content (0.40%). Lithium, Ga, Se, Zr and Hf present strongly positive correlation with ash yield, Si and Al, suggesting they are associated with aluminosilicate minerals in the No. 5 coal. Arsenic is only weakly associated with mineral matter and Ge in the No. 5 coals might be of organic and/or sulfide affinity