A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands
- Sébastien Goeb
DOIAbstract
Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)2 (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized
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