An on-column HPLC procedure using a chiral stationary phase (CSP) was developed for the determination of rate constants and free energy barriers of enantiomerization of (+/-)IDRA21. Subsequently, the HPLC method was applied for investigation of two structurally related chiral compounds. The individual enantiomers of the studied compounds were isolated in parallel by preparative HPLC and rate constants and free energy barriers of enantiomerization were determined in different solvents. The on-column enantiomerization data revealed that CSP induces different rate constants for the two enantiomers. The results generated off-line were used to determine the influence of solvents on the racemization of (+) and (-) IDRA21 and to gain further insig...
A novel stopped-flow multidimensional HPLC (sf-MD-HPLC) procedure has been developed to investigate ...
On-column stopped flow multidimensional HPLC (sfMDHPLC) anddynamic high-performance liquid chromatog...
On-column stopped flow multidimensional HPLC (sfMDHPLC) anddynamic high-performance liquid chromatog...
An on-column HPLC procedure using a chiral stationary phase (CSP) was developed for the determinatio...
The synthesis and enantioseparation of chiral 3,4-dihydro-1,2,4-benzothiadiazine 1,1-dioxide derivat...
The synthesis and enantioseparation of chiral 3,4-dihydro-1,2,4-benzothiadiazine 1,1-dioxide derivat...
An on-column stopped-flow multidimensional HPLC (sfMDHPLC) procedure using two chiral stationaryphas...
An on-column stopped-flow multidimensional HPLC (sfMDHPLC) procedure using two chiral stationaryphas...
Analytical high-performance liquid chromatography (HPLC) methods using derivatized cellulose chiral ...
Analytical high-performance liquid chromatography (HPLC) methods using derivatized cellulose chiral ...
A stopped-flow bidimensional recycle HPLC (sf-BD-rHPLC) configuration has been used to investigate s...
A stopped-flow bidimensional recycle HPLC (sf-BD-rHPLC) configuration has been used to investigate s...
An on-column stopped-flow bidimensional recycling HPLC procedure was developed to obtain an enantiom...
An on-column stopped-flow bidimensional recycling HPLC procedure was developed to obtain an enantiom...
A novel stopped-flow multidimensional HPLC (sf-MD-HPLC) procedure has been developed to investigate ...
A novel stopped-flow multidimensional HPLC (sf-MD-HPLC) procedure has been developed to investigate ...
On-column stopped flow multidimensional HPLC (sfMDHPLC) anddynamic high-performance liquid chromatog...
On-column stopped flow multidimensional HPLC (sfMDHPLC) anddynamic high-performance liquid chromatog...
An on-column HPLC procedure using a chiral stationary phase (CSP) was developed for the determinatio...
The synthesis and enantioseparation of chiral 3,4-dihydro-1,2,4-benzothiadiazine 1,1-dioxide derivat...
The synthesis and enantioseparation of chiral 3,4-dihydro-1,2,4-benzothiadiazine 1,1-dioxide derivat...
An on-column stopped-flow multidimensional HPLC (sfMDHPLC) procedure using two chiral stationaryphas...
An on-column stopped-flow multidimensional HPLC (sfMDHPLC) procedure using two chiral stationaryphas...
Analytical high-performance liquid chromatography (HPLC) methods using derivatized cellulose chiral ...
Analytical high-performance liquid chromatography (HPLC) methods using derivatized cellulose chiral ...
A stopped-flow bidimensional recycle HPLC (sf-BD-rHPLC) configuration has been used to investigate s...
A stopped-flow bidimensional recycle HPLC (sf-BD-rHPLC) configuration has been used to investigate s...
An on-column stopped-flow bidimensional recycling HPLC procedure was developed to obtain an enantiom...
An on-column stopped-flow bidimensional recycling HPLC procedure was developed to obtain an enantiom...
A novel stopped-flow multidimensional HPLC (sf-MD-HPLC) procedure has been developed to investigate ...
A novel stopped-flow multidimensional HPLC (sf-MD-HPLC) procedure has been developed to investigate ...
On-column stopped flow multidimensional HPLC (sfMDHPLC) anddynamic high-performance liquid chromatog...
On-column stopped flow multidimensional HPLC (sfMDHPLC) anddynamic high-performance liquid chromatog...