Add to ORKGAn investigation of the solid-state conformational properties of 3-methylsulphinyl derivatives of furan and 2- and 3-methylsulphinyl derivatives of thiophene, which also contain halogen atoms in the heterocyclic ring, is reported. For 3-iodo-2-(methylsulphinyl)thiophene, compound 1, two crystallographically independent molecules were found in the unit cell, and in 2-bromo-4-iodo-3-(methylsulphinyl)thiophene, compound 5, a high degree of disorder is present. The sulphur atom of the methylsulphinyl group has a pyramidal structure. The methyl group is highly twisted with respect to the ring plane and the S-O bond adopts different orientations in the molecules examined. When only one halogen atom is present in the ring the S-O bond is direc...
Ab initio MO calculations (3-21G*//3-lG* basis set) have been performed for methylphenyl sulphoxide ...
There are two symmetry-independent molecules in the asymmetric unit of the title compound, C13H13IO4...
The X-ray single crystal analysis of isomeric ortho, meta, and para bromo-substituted α-methylsulfon...
An investigation of the solid-state conformational properties of 3-methylsulphinyl derivatives of fu...
The preferred conformations of the methylsulphinyl group bonded to the heterocycles furan and thioph...
The ground state conformations and transition states for conformer interconversion in the two isomer...
The solid-state crystal and molecular structure of a number of ring-substituted methyl phenyl sulfox...
Relaxation parameters such as nuclear Overhauser effect (NOE) and spin-lattice relaxation times (T1)...
The conformational properties of the title compounds, which are the basic head-to-head, head-to-tail...
The conformational equilibrium of 2-(2' -ethylsulfanyl)acetyl-5-substituted furans and thiophenes [E...
A number of ring-substituted methyl phenyl sulphoxides have been examined with a multinuclear n.m.r....
The X-ray structure of the title compound has been determined for the first time. It shows the ring ...
The X-ray structure of the title compound has been determined for the first time. It shows the ring ...
A number of ring-substituted methyl phenyl sulphoxides have been examined with a multinuclear n.m.r....
The structures of the isomeric 2,5-dihydrothiophene 1,1-dioxide [orthorhombic, a = 11.340(2), b = 7....
Ab initio MO calculations (3-21G*//3-lG* basis set) have been performed for methylphenyl sulphoxide ...
There are two symmetry-independent molecules in the asymmetric unit of the title compound, C13H13IO4...
The X-ray single crystal analysis of isomeric ortho, meta, and para bromo-substituted α-methylsulfon...
An investigation of the solid-state conformational properties of 3-methylsulphinyl derivatives of fu...
The preferred conformations of the methylsulphinyl group bonded to the heterocycles furan and thioph...
The ground state conformations and transition states for conformer interconversion in the two isomer...
The solid-state crystal and molecular structure of a number of ring-substituted methyl phenyl sulfox...
Relaxation parameters such as nuclear Overhauser effect (NOE) and spin-lattice relaxation times (T1)...
The conformational properties of the title compounds, which are the basic head-to-head, head-to-tail...
The conformational equilibrium of 2-(2' -ethylsulfanyl)acetyl-5-substituted furans and thiophenes [E...
A number of ring-substituted methyl phenyl sulphoxides have been examined with a multinuclear n.m.r....
The X-ray structure of the title compound has been determined for the first time. It shows the ring ...
The X-ray structure of the title compound has been determined for the first time. It shows the ring ...
A number of ring-substituted methyl phenyl sulphoxides have been examined with a multinuclear n.m.r....
The structures of the isomeric 2,5-dihydrothiophene 1,1-dioxide [orthorhombic, a = 11.340(2), b = 7....
Ab initio MO calculations (3-21G*//3-lG* basis set) have been performed for methylphenyl sulphoxide ...
There are two symmetry-independent molecules in the asymmetric unit of the title compound, C13H13IO4...
The X-ray single crystal analysis of isomeric ortho, meta, and para bromo-substituted α-methylsulfon...