The kinetic rate of dechlorination of a polychlorinated biphenyl (PCB-151) by mechanically alloyed Mg/Pd was studied for optimization of the bimetallic system. Bimetal production was first carried out in a small-scale environment using a SPEX 8000M high-energy ball mill with 4-μm-magnesium and palladium impregnated on graphite, with optimized parameters including milling time and Pd-loading. A 5.57-g sample of bimetal containing 0.1257% Pd and ball milled for 3min resulted in a degradation rate of 0.00176min -1g -1 catalyst as the most reactive bimetal. The process was then scaled-up, using a Red Devil 5400 Twin-Arm Paint Shaker, fitted with custom plates to hold milling canisters. Optimization parameters tested included milling time, numbe...
It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutan...
Polybrominated diphenyl ethers (PBDEs) are a group of widely used brominated flame retardants. Due t...
Polychlorinated biphenyls (PCBs) were widely used in industry until their regulation in the 1970s. H...
The kinetic rate of dechlorination of a polychlorinated biphenyl (PCB-151) by mechanically alloyed M...
The combination of zero-valent metals and hydrogenation catalysts, specifically mechanically alloyed...
The combination of zero-valent metals and hydrogenation catalysts, specifically mechanically alloyed...
Polychlorinated biphenyls (PCBs) are a continuing concern in the environment, although legislation r...
Polychlorinated biphenyls (PCBs) are a continuing concern in the environment, although legislation r...
Following the 1976 Toxic Substances Control Act ban on their manufacture, PCBs remain an environment...
Polychlorinated biphenyls are a ubiquitous environmental contaminant that can be found today through...
The contamination of sediments with polychlorinated organics such as polychlorinated biphenyls (PCBs...
It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutan...
It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutan...
Polybrominated diphenyl ethers (PBDEs) are a group of widely used brominated flame retardants. Due t...
Ninety-four percent removal of 10 mg L−1 of pentachlorophenol (PCP) was achieved by treatment with 1...
It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutan...
Polybrominated diphenyl ethers (PBDEs) are a group of widely used brominated flame retardants. Due t...
Polychlorinated biphenyls (PCBs) were widely used in industry until their regulation in the 1970s. H...
The kinetic rate of dechlorination of a polychlorinated biphenyl (PCB-151) by mechanically alloyed M...
The combination of zero-valent metals and hydrogenation catalysts, specifically mechanically alloyed...
The combination of zero-valent metals and hydrogenation catalysts, specifically mechanically alloyed...
Polychlorinated biphenyls (PCBs) are a continuing concern in the environment, although legislation r...
Polychlorinated biphenyls (PCBs) are a continuing concern in the environment, although legislation r...
Following the 1976 Toxic Substances Control Act ban on their manufacture, PCBs remain an environment...
Polychlorinated biphenyls are a ubiquitous environmental contaminant that can be found today through...
The contamination of sediments with polychlorinated organics such as polychlorinated biphenyls (PCBs...
It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutan...
It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutan...
Polybrominated diphenyl ethers (PBDEs) are a group of widely used brominated flame retardants. Due t...
Ninety-four percent removal of 10 mg L−1 of pentachlorophenol (PCP) was achieved by treatment with 1...
It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutan...
Polybrominated diphenyl ethers (PBDEs) are a group of widely used brominated flame retardants. Due t...
Polychlorinated biphenyls (PCBs) were widely used in industry until their regulation in the 1970s. H...