We study the interface between liquid and vapor in the context of the van der Waals theory, considering the non-local free energy functional recently derived by Lebowitz, Mazel, and Presutti from a system of particles in the continuum with Kac potentials. We prove that the density profile between vapor and liquid is monotone when the inverse temperature is between the critical value beta(c) and a second critical value beta*>beta(c), becoming oscillatory after beta* and overshooting the equilibrium density of the liquid phase infinitely often
A classical gas whose particles interact through a weak long range attraction and short range repuls...
The adsorption of a molecule at the liquid–vapor interface is a complex phenomenon that is influence...
Within the first part the interfacial wetting behaviour of binary liquid mixtures at their liquid-va...
We study the interface between liquid and vapor in the context of the van der Waals theory, consider...
We study the interface between liquid and vapor in the context of the van der Waals theory, consider...
Includes bibliographical references (pages 49-50)The nature of the density profile in the vicinity o...
International audienceThanks to an expansion with respect to densities of energy, mass and entropy, ...
Includes bibliographical references (page 44)The variation of local density with position in the int...
In their seminal monograph ’Molecular Theory of Capillarity’, Rowlinson and Widom describe different...
We simulate liquid-vapor phase separation in a van der Waals fluid that is deeply quenched into the ...
A Helmholtz energy functional for inhomogeneous fluid phases based on the perturbed-chain polar stat...
A vapor-liquid interface introduces resistivities for mass and heat transfer. These resistivities ha...
A Helmholtz energy functional for inhomogeneous fluid phases based on the perturbed-chain polar stat...
In separation processes not only thermodynamic bulk but also interfacial properties play a crucial r...
A classical gas whose particles interact through a weak long range attraction and short range repuls...
A classical gas whose particles interact through a weak long range attraction and short range repuls...
The adsorption of a molecule at the liquid–vapor interface is a complex phenomenon that is influence...
Within the first part the interfacial wetting behaviour of binary liquid mixtures at their liquid-va...
We study the interface between liquid and vapor in the context of the van der Waals theory, consider...
We study the interface between liquid and vapor in the context of the van der Waals theory, consider...
Includes bibliographical references (pages 49-50)The nature of the density profile in the vicinity o...
International audienceThanks to an expansion with respect to densities of energy, mass and entropy, ...
Includes bibliographical references (page 44)The variation of local density with position in the int...
In their seminal monograph ’Molecular Theory of Capillarity’, Rowlinson and Widom describe different...
We simulate liquid-vapor phase separation in a van der Waals fluid that is deeply quenched into the ...
A Helmholtz energy functional for inhomogeneous fluid phases based on the perturbed-chain polar stat...
A vapor-liquid interface introduces resistivities for mass and heat transfer. These resistivities ha...
A Helmholtz energy functional for inhomogeneous fluid phases based on the perturbed-chain polar stat...
In separation processes not only thermodynamic bulk but also interfacial properties play a crucial r...
A classical gas whose particles interact through a weak long range attraction and short range repuls...
A classical gas whose particles interact through a weak long range attraction and short range repuls...
The adsorption of a molecule at the liquid–vapor interface is a complex phenomenon that is influence...
Within the first part the interfacial wetting behaviour of binary liquid mixtures at their liquid-va...