The fate of iron in waters from a coastal environment impacted by metallurgical industry in Northern Italy: hydrochemistry and Fe-isotopes.

The source and cycling of Fe in groundwaters from the phreatic aquifer which characterizes a site impacted by metallurgical activity in a coastal area of northern Italy (Adriatic Sea) have been investigated by Fe-isotope analyses, H\u2013O\u2013Sr stable-isotope systematics and major and trace element chemistry. Waters are characterized by circum-neutral to alkaline pH and dissolved O2 zoning, and range from a low-salinity Ca\u2013Mg\u2013HCO3 type to a brackish Na\u2013Cl type resulting from seawater intrusion. The O\u2013H isotopic data indicate that the Ca\u2013Mg\u2013HCO3 waters originate from meteoric precipitation that infiltrated at elevated altitudes, and that a variable seawater fraction, in some cases exceeding 90%, characterizes the Na\u2013Cl type waters. The Fe content ranges from 0.48 to 9.99 mg/L and from 2.50 to 43.8 mg/L in low-salinity and brackish waters, respectively. The \uf06456Fe value varies over the wide range from +0.87\u2030 to 5.29\u2030 in low-salinity waters and between +2.15\u2030 and 2.34\u2030 in brackish waters. The isotopically lighter compositions are interpreted as reflecting isotopic fractionation during repeated cycling of Fe precipitation. Positive \uf06456Fe values might indicate either a higher solubility of oxyhydroxides, which during diagenesis preferentially incorporated the isotopically heavier fraction of Fe, or the leaching of the foundry landfill disposal which characterizes the site