DIFFRACTION AND XPS STUDIES OF CU COMPLEXES OF INTERCALATED COMPOUNDS OF ALPHA-ZIRCONIUM PHOSPHATE .1. DERIVATION OF STRUCTURAL MODELS FROM POWDER DIFFRACTION DATA

DEPERO L.E.
ZOCCHI M.
PARMIGIANI F.
LAGINESTRA A.
MASSUCCI M.A.

Publication date

January 1994

Abstract

Reasonable structural models are proposed for the Cu complexes of two intercalated compounds of alpha-Zr(HPO4)2 . H2O (alpha-ZrP): one with 1,10-phenanthroline (A) and the other with 2,2'-bipyridyl (B). The models are derived from considerations of the unit-cell geometry changes undergone by alpha-ZrP upon insertion of, first, the organic molecules and then copper, in accordance with a set of general criteria of structural analysis called the ''comparison method. '

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DIFFRACTION AND XPS STUDIES OF CU COMPLEXES OF INTERCALATED COMPOUNDS OF ALPHA-ZIRCONIUM PHOSPHATE .1. DERIVATION OF STRUCTURAL MODELS FROM POWDER DIFFRACTION DATA

Abstract

Extracted data

DIFFRACTION AND XPS STUDIES OF CU COMPLEXES OF INTERCALATED COMPOUNDS OF ALPHA-ZIRCONIUM PHOSPHATE .1. DERIVATION OF STRUCTURAL MODELS FROM POWDER DIFFRACTION DATA

Abstract

Extracted data

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