Results of the QUENCH-20 experiment with BWR test bundle [in press]

The experiment QUENCH-20 with BWR geometry simulation bundle was successfully conducted at KIT on 9th October 2019 in the framework of the international SAFEST project. The test bundle mock-up represented one quarter of a BWR fuel assembly with 24 electrically heated fuel rod simulators and two B4C control blades. The rod simulators were filled with Kr to an inner pressure of 5.5 bar. The pre-oxidation stage in a flowing gas mixture of steam and argon (each 3 g/s) and system pressure of 2 bar lasted 4 hours at the peak cladding temperature of 1250 K. The Zry-4 corner rod, withdrawn at the end of this stage, showed the maximal oxidation at elevations between 930 and 1020 mm with signs of breakaway. During the transient stage, the bundle was heated to a maximum temperature of 2000 K. The coolability of the bundle was decreased by its squeezing due to the shroud ductile deformation caused by an overpressure outside the shroud. The cladding radial strain and failures due to inner overpressure (about 4 bar) were observed at temperature about 1700 K and lasted about 200 s. During the period of rod failures also the first absorber melt relocation accompanied by shroud failure were registered. The interaction of B4C with the steel blade and the ZIRLO channel box were observed at elevations 650…950 mm with the formation of eutectic melt. The typical components of this melt are (Fe, Cr) borides and ZrB2 precipitated in steel or in Zr-steel eutectic melt. Massive absorber melt relocation was observed 50 s before the end of transition stage. Small fragments of the absorber melt moved down to the elevation of 50 mm. The melting point of Inconel spacer grids at 500 and 1050 mm was also reached at the end of the transition stage. The Inconel melt from the elevation 1050 mm relocated downwards through hot bundle regions to the Inconel grid spacer at 550 mm and later (during the escalation caused by quench) to 450 mm. This melt penetrated also under the damaged cladding oxide layer and formed molten eutectic mixtures between elevations 450 and 550 mm. The test was terminated by quench water injection with a flow rate of 50 g/s from the bundle bottom. Fast temperature escalation from 2000 to 2300 K during 20 s was observed due to the strongly exothermic oxidation reactions. As result, the metal part (prior β-Zr) of the claddings between 550 and 950 mm was melted, partially released into space between rods and partially relocated in the gap between pellet and outer oxide layer to 450 mm. In this case, the positive role of the oxide layer should be noted, which does not allow the melt to completely escape into the inter-rod space. It is thereby limiting the possibility of interactions of a large amount of melt with steam, which could significantly increase the exothermic oxidation processes and the escalation of temperatures. The distribution of the oxidation rate within each bundle cross section is very inhomogeneous: whereas the average outer ZrO2 layer thickness for the central rod (#1) at the elevation of 750 mm is 465 µm, the same parameter for the peripheral rod #24 is only 108 µm. The average oxidation rate of the inner cladding surface (due to interaction with steam and with ZrO2 pellets) is about 20% in comparison to the outer cladding oxidation. The bundle elevations 850 and 750 mm are mostly oxidized with average cladding ECR 33%. The oxidation of the melt relocated inside the rods was observed at elevations 550…950 mm. The mass spectrometer measured release of CO (12.6 g), CO2 (9.7 g) and CH4 (0.4 g) during the reflood as products of absorber oxidation; the corresponding B4C reacted mass was 41 g or 4.6% of the total B4C inventory. It is significantly lower than in the PWR bundle tests QUENCH-07 and QUENCH-09 containing central absorber rod with B4C pellets inserted into a thin stainless steel cladding and Zry-4 guide tubes (20% and 50% reacted B4C correspondingly). Hydrogen production during the reflood amounted to 32 g during the reflood (57.4 g during the whole test) including 10 g from B4C oxidation