International audienceThe vast majority of the geological constraints (i.e., internal structure via the density, cratering history) for main belt asteroids have so far been obtained via dedicated interplanetary missions (e.g., Rosetta, DAWN). The high angular resolution of SPHERE/ZIMPOL (one pixel represents 3.6 x 3.6 mas on sky), the new-generation visible adaptive-optics camera at ESO/VLT, implies that such science objective can now be investigated from the ground for a large fraction of D>=100 km main-belt asteroids (most of these bodies possess an angular diameter around opposition larger than 100 mas). The sharp images acquired by this instrument can be used to constrain accurately the shape and thus volume of these bodies (hence de...