Controlled Aqueous Atom Transfer Radical Polymerization with Electrochemical Generation of the Active Catalyst

Bortolamei, Nicola
AHMED ISSE, Abdirisak
Andrew J. D., Magenau
Gennaro, Armando
Krzysztof, Matyjaszewski

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Publication date

January 2011

DOI

10.1002/anie.201105317

Publisher

Wiley

ISSN

1433-7851

Citation count (estimate)

130

Abstract

Electrochemically mediated ATRP (eATRP) allows easy modulation of the overall rate and control of polymerization through the variation of an external applied potential, Eapp. This method has been successfully applied to aqueous ATRP of oligo(ethylene glycol) methyl ether methacrylate (OEOMA475) catalyzed by Cu/TPMA. Appropriate choice of Eapp allows the synthesis of POEOMA475 with high Mw, and narrow MW distribution

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Controlled Aqueous Atom Transfer Radical Polymerization with Electrochemical Generation of the Active Catalyst

Abstract

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Controlled Aqueous Atom Transfer Radical Polymerization with Electrochemical Generation of the Active Catalyst

Abstract

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