Single-Site vs. Cluster Catalysis in High Temperature Oxidations

The behavior of single Pt atoms and small Pt clusters was investigated for high-temperature oxidations. The high stability of these molecular sites in CHA is a key to intrinsic structure–performance descriptions of elemental steps such as O dissociation, and subsequent oxidation catalysis. Subtle changes in the atomic structure of Pt are responsible for drastic changes in performance driven by specific gas/metal/support interactions. Whereas single Pt atoms and Pt clusters (> ca. 1 nm) are unable to activate, scramble, and desorb two O molecules at moderate T (200 °C), clusters